{"title":"Cover Feature: Stable and Versatile Pd Precursors for the Preparation of Robust Pd Catalysts Under Continuous-Flow (ChemSusChem 4/2025)","authors":"Naoya Sakurada, Kwihwan Kobayashi, Yuka Abe, Kosuke Niwa, Takashi Yokoyama, Tsuyoshi Yamada, Takashi Ikawa, Hironao Sajiki","doi":"10.1002/cssc.202580402","DOIUrl":null,"url":null,"abstract":"<p><b>A new Pd precursor</b> (Pd-80), prepared by the thermally promoted aerobic oxidation of tetrakis(triphenylphosphine)palladium, has been developed to efficiently incorporate Pd metal nanoclusters into supports. Pd species can be easily immobilized on various inorganic and organic supports by using Pd-80. This image shows the moment when nanoclusters are loaded onto cordierite. Pd/cordierite specifically catalyzed the hydrogenation of various reducible functional groups under continuous-flow conditions. More information can be found in the Research Article by T. Ikawa, H. Sajiki and co-workers.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":"18 4","pages":""},"PeriodicalIF":6.6000,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cssc.202580402","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemSusChem","FirstCategoryId":"92","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202580402","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A new Pd precursor (Pd-80), prepared by the thermally promoted aerobic oxidation of tetrakis(triphenylphosphine)palladium, has been developed to efficiently incorporate Pd metal nanoclusters into supports. Pd species can be easily immobilized on various inorganic and organic supports by using Pd-80. This image shows the moment when nanoclusters are loaded onto cordierite. Pd/cordierite specifically catalyzed the hydrogenation of various reducible functional groups under continuous-flow conditions. More information can be found in the Research Article by T. Ikawa, H. Sajiki and co-workers.
研究了一种新的钯前驱体(Pd-80),该前驱体是由四(三苯基膦)钯热促进有氧氧化制备的,可以有效地将钯金属纳米团簇结合到载体中。Pd-80可以很容易地将Pd固定在各种无机和有机载体上。这张图片显示了纳米团簇被加载到堇青石上的瞬间。Pd/堇青石在连续流动条件下特异性催化多种可还原官能团的加氢反应。更多信息可以在T. Ikawa, H. Sajiki及其同事的研究文章中找到。
期刊介绍:
ChemSusChem
Impact Factor (2016): 7.226
Scope:
Interdisciplinary journal
Focuses on research at the interface of chemistry and sustainability
Features the best research on sustainability and energy
Areas Covered:
Chemistry
Materials Science
Chemical Engineering
Biotechnology