{"title":"Fabrication of Highly Efficient Nanogold Membrane Catalysts Utilizing Ultrathin Gold Nanowires in the Presence of Thiourea","authors":"Yulu Ye, Jiahang Zhou, Minqiang Xia, Yunbo Li","doi":"10.1021/acs.jpcc.4c07999","DOIUrl":null,"url":null,"abstract":"Membrane catalysts have garnered considerable attention in recent years owing to their outstanding stability, high recyclability, environmental compatibility, and convenience. Herein, nanogold membrane catalysts have been successfully fabricated with ultrathin gold nanowires in the presence of thiourea by a vacuum filtration deposition method aimed at facilitating charge transport and enhancing the catalytic performance. By maintaining the thiourea treatment concentration at 500 μg/mL, the catalytic time of the nanogold membrane remained below 1.0 min for 2-nitrophenol, specifically at 15 s. The 500 μg/mL thiourea-treated nanogold membranes are also capable of rapidly catalyzing the reduction of 4-nitrophenol, methylene blue, and methyl orange, causing their respective UV characteristic peaks to disappear expeditiously within 20 s. Overall, this novel method offers a simple and convenient approach to obtaining nanogold membrane catalysts, holding great potential promise for applications in materials, catalysts, and environment fields.","PeriodicalId":61,"journal":{"name":"The Journal of Physical Chemistry C","volume":"20 1","pages":""},"PeriodicalIF":3.3000,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of Physical Chemistry C","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.jpcc.4c07999","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Membrane catalysts have garnered considerable attention in recent years owing to their outstanding stability, high recyclability, environmental compatibility, and convenience. Herein, nanogold membrane catalysts have been successfully fabricated with ultrathin gold nanowires in the presence of thiourea by a vacuum filtration deposition method aimed at facilitating charge transport and enhancing the catalytic performance. By maintaining the thiourea treatment concentration at 500 μg/mL, the catalytic time of the nanogold membrane remained below 1.0 min for 2-nitrophenol, specifically at 15 s. The 500 μg/mL thiourea-treated nanogold membranes are also capable of rapidly catalyzing the reduction of 4-nitrophenol, methylene blue, and methyl orange, causing their respective UV characteristic peaks to disappear expeditiously within 20 s. Overall, this novel method offers a simple and convenient approach to obtaining nanogold membrane catalysts, holding great potential promise for applications in materials, catalysts, and environment fields.
期刊介绍:
The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.