Fabrication of Highly Efficient Nanogold Membrane Catalysts Utilizing Ultrathin Gold Nanowires in the Presence of Thiourea

IF 3.2 3区 化学 Q2 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry C Pub Date : 2025-02-14 DOI:10.1021/acs.jpcc.4c07999
Yulu Ye, Jiahang Zhou, Minqiang Xia, Yunbo Li
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Abstract

Membrane catalysts have garnered considerable attention in recent years owing to their outstanding stability, high recyclability, environmental compatibility, and convenience. Herein, nanogold membrane catalysts have been successfully fabricated with ultrathin gold nanowires in the presence of thiourea by a vacuum filtration deposition method aimed at facilitating charge transport and enhancing the catalytic performance. By maintaining the thiourea treatment concentration at 500 μg/mL, the catalytic time of the nanogold membrane remained below 1.0 min for 2-nitrophenol, specifically at 15 s. The 500 μg/mL thiourea-treated nanogold membranes are also capable of rapidly catalyzing the reduction of 4-nitrophenol, methylene blue, and methyl orange, causing their respective UV characteristic peaks to disappear expeditiously within 20 s. Overall, this novel method offers a simple and convenient approach to obtaining nanogold membrane catalysts, holding great potential promise for applications in materials, catalysts, and environment fields.

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硫脲存在下利用超薄金纳米线制备高效纳米金膜催化剂
近年来,膜催化剂因其优异的稳定性、高可回收性、环境相容性和便利性而受到广泛关注。本文采用真空过滤沉积的方法,在硫脲存在的情况下,成功制备了超薄金纳米线纳米金膜催化剂,旨在促进电荷传输和提高催化性能。当硫脲处理浓度维持在500 μg/mL时,纳米金膜对2-硝基苯酚的催化时间保持在1.0 min以下,特别是在15 s。500 μg/mL硫脲处理的纳米金膜还能快速催化4-硝基苯酚、亚甲基蓝和甲基橙的还原,使其各自的紫外特征峰在20 s内迅速消失。总之,该方法为制备纳米金膜催化剂提供了一种简单、方便的方法,在材料、催化剂和环境等领域具有广阔的应用前景。
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阿拉丁
Oleylamine
阿拉丁
n-hexane
阿拉丁
Triisopropylsilane
来源期刊
The Journal of Physical Chemistry C
The Journal of Physical Chemistry C 化学-材料科学:综合
CiteScore
6.50
自引率
8.10%
发文量
2047
审稿时长
1.8 months
期刊介绍: The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.
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