Han Yang , Fu-Chang Liang , Bo Tang, Hai-Xiong Chen, Si-Yun Fu, Song-Liang Cai, Wei-Guang Zhang, Jun Fan, Sheng-Run Zheng
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引用次数: 0
Abstract
The development of a chiral stationary phase (CSP) based on new matrices is still necessary because of the rapid growth of new chiral drugs and the limitations of the silica gel matrix. For the first time, MOF glass agZIF-62 was used as a matrix to fabricate a chiral stationary phase (CSP) by coating cellulose-tris(3,5-dimethylphenylcarbamate) (CDMPC). These MOF glass-based CSPs can separate various racemic compounds, including metalaxyl, epoxiconazole, TSO, cis-metconazole, and triticonazole with resolution values (Rs) ranging from 1.22 to 4.58 and separation factors (α) ranging from 1.8 to 6.79. In addition, the HPLC enantiomer separation performances of MOF glass-based and MOF crystal-based CSPs were compared.
期刊介绍：
Covering major developments in the field of solid state chemistry and related areas such as ceramics and amorphous materials, the Journal of Solid State Chemistry features studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids.
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