A. V. Gudymenko, V. A. Komornikov, N. I. Sorokina, T. A. Sorokin, I. S. Timakov, D. S. Matveeva, A. E. Voloshin
{"title":"Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal","authors":"A. V. Gudymenko, V. A. Komornikov, N. I. Sorokina, T. A. Sorokin, I. S. Timakov, D. S. Matveeva, A. E. Voloshin","doi":"10.1134/S1063774524602089","DOIUrl":null,"url":null,"abstract":"<p>Rb<sub>3</sub>CoCl<sub>4</sub>NO<sub>3</sub> samples applicable for studying spectral characteristics have been obtained for the first time and investigated in the wavelength range λ = 200–800 nm. Transparency windows are found at the UV–visible and visible–IR boundaries. Differential-scanning calorimetry/thermogravimetry analysis revealed that the Rb<sub>3</sub>CoCl<sub>4</sub>NO<sub>3</sub> crystal is thermally stable, melts without decomposition, and undergoes two reversible phase transitions. The structure of Rb<sub>3</sub>CoCl<sub>4</sub>NO<sub>3</sub> single crystals was studied by X-ray diffraction in the temperature range of 293–625 K.</p>","PeriodicalId":527,"journal":{"name":"Crystallography Reports","volume":"69 7","pages":"1035 - 1044"},"PeriodicalIF":0.6000,"publicationDate":"2025-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystallography Reports","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1063774524602089","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0
Abstract
Rb3CoCl4NO3 samples applicable for studying spectral characteristics have been obtained for the first time and investigated in the wavelength range λ = 200–800 nm. Transparency windows are found at the UV–visible and visible–IR boundaries. Differential-scanning calorimetry/thermogravimetry analysis revealed that the Rb3CoCl4NO3 crystal is thermally stable, melts without decomposition, and undergoes two reversible phase transitions. The structure of Rb3CoCl4NO3 single crystals was studied by X-ray diffraction in the temperature range of 293–625 K.
期刊介绍：
Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
