Structure, Spectral Characteristics, and Phase Transitions in the Rb3CoCl4NO3 Crystal

IF 0.5 4区 材料科学 Q4 CRYSTALLOGRAPHY Crystallography Reports Pub Date : 2025-02-16 DOI:10.1134/S1063774524602089
A. V. Gudymenko, V. A. Komornikov, N. I. Sorokina, T. A. Sorokin, I. S. Timakov, D. S. Matveeva, A. E. Voloshin
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Abstract

Rb3CoCl4NO3 samples applicable for studying spectral characteristics have been obtained for the first time and investigated in the wavelength range λ = 200–800 nm. Transparency windows are found at the UV–visible and visible–IR boundaries. Differential-scanning calorimetry/thermogravimetry analysis revealed that the Rb3CoCl4NO3 crystal is thermally stable, melts without decomposition, and undergoes two reversible phase transitions. The structure of Rb3CoCl4NO3 single crystals was studied by X-ray diffraction in the temperature range of 293–625 K.

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Rb3CoCl4NO3晶体的结构、光谱特性和相变
首次获得了适用于光谱特性研究的Rb3CoCl4NO3样品,并在λ = 200-800 nm波长范围内进行了研究。透明窗口位于紫外可见和可见-红外边界。差示扫描量热/热重分析表明,Rb3CoCl4NO3晶体热稳定,熔体不分解,经历了两次可逆相变。在293 ~ 625 K的温度范围内,用x射线衍射研究了Rb3CoCl4NO3单晶的结构。
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来源期刊
Crystallography Reports
Crystallography Reports 化学-晶体学
CiteScore
1.10
自引率
28.60%
发文量
96
审稿时长
4-8 weeks
期刊介绍: Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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