Soft template-induced deep pore structure of Cu/Al2O3 for promoting plasma-catalyzed CO2 hydrogenation to DME

IF 10.8 2区 化学 Q1 CHEMISTRY, PHYSICAL 物理化学学报 Pub Date : 2025-01-25 DOI:10.1016/j.actphy.2025.100054
Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji
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Abstract

Plasma-activated heterogeneous catalysis is a promising strategy for catalytic CO2 hydrogenation under mild conditions. In this study, pore structures with deep pore channels were constructed on Al2O3-x via a soft template method, and Cu/Al2O3-x was prepared by an impregnation method, with Al2O3-x serving as the support for plasma-catalyzed CO2 hydrogenation to dimethyl ether (DME). Cu/Al2O3-0.75/HZSM-5 demonstrated a high performance and discharge efficiency for plasma-catalyzed CO2 hydrogenation. The CO2 conversion and DME yield for plasma-catalyzed CO2 hydrogenation on Cu/Al2O3-0.75/HZSM-5 reached 21.98% and 9.83%, respectively, with selectivities for CO, CH3OH, and DME on Cu/Al2O3-0.75/HZSM-5 of 25.39%, 29.89%, and 44.72%, respectively. The deep pore structures on Al2O3-x serve as Cu loading sites, and the confinement effect of the pores enhances the metal-support interaction and Cu metal dispersion. More abundant and stronger Brønsted basic and Lewis acidic sites facilitate the activation and hydrogenation of CO2. Notably, the electric field formed by Cu sites anchored in the deep pore channel structures is conducive to guiding the activated plasma CO2 intermediates into the difficult-to-access pores for hydrogenation. Hydrogenation of the plasma-activated CO2 intermediates in the deep pore channels is crucial for improving plasma-catalyzed CO2 hydrogenation to DME.

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物理化学学报
物理化学学报 化学-物理化学
CiteScore
16.60
自引率
5.50%
发文量
9754
审稿时长
1.2 months
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