Sorption of Tetravalent Actinides from Nitric Acid Process Solutions Using Anion-Exchange Resins Produced by Smoly Group of Enterprises

IF 1 Q4 CHEMISTRY, INORGANIC & NUCLEAR Radiochemistry Pub Date : 2025-02-17 DOI:10.1134/S1066362224060080
E. V. Lyzlova, A. V. Glukhova, L. V. Chernavskaya, A. V. Konnikov, M. S. Lysenko
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Abstract

The possibility of using new anion-exchange resins AM-4VP, AM_pu, AMP-p, AM-p, and AM-2B produced by Smoly Group of Enterprises for plutonium recovery from nitric acid process solutions was examined. The physicochemical characteristics of the resins, the thorium distribution coefficients as functions of the nitric acid concentration, and the static exchange capacities of the resins were determined. The plutonium recovery from process solutions was studied in column experiments. The physicochemical properties and sorption ability of the anion-exchange resins were compared to those of the previously used VP-1Ap resin. AM-4VP resin shows promise for plutonium recovery from nitric acid process solutions.

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用斯莫里集团生产的阴离子交换树脂吸附硝酸工艺溶液中的四价锕系元素
考察了用斯莫里集团生产的新型阴离子交换树脂AM-4VP、AM_pu、AMP-p、AM-p和AM-2B回收硝酸工艺液中钚的可能性。测定了树脂的理化性质、钍分布系数随硝酸浓度的变化规律以及树脂的静态交换能力。采用柱式实验对工艺液中钚的回收进行了研究。研究了阴离子交换树脂的物理化学性能和吸附性能,并与已有的VP-1Ap树脂进行了比较。AM-4VP树脂有望从硝酸工艺溶液中回收钚。
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来源期刊
Radiochemistry
Radiochemistry CHEMISTRY, INORGANIC & NUCLEAR-
CiteScore
1.30
自引率
33.30%
发文量
51
期刊介绍: Radiochemistry  is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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