Using low concentration polyethylene glycol to regulate the microstructure of ink to improve the printing quality of cotton fabric

IF 4.8 2区 工程技术 Q1 MATERIALS SCIENCE, PAPER & WOOD Cellulose Pub Date : 2025-01-23 DOI:10.1007/s10570-024-06366-x
Zhiyuan Tang, Xueyuan Yang, Fuyun Sun, Kun Zhang, Kuanjun Fang
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Abstract

Satellite droplets, excessive ink spreading and penetration present significant obstacles to the advancement of inkjet printing on cotton fabrics. Traditional ink preparation methods utilizing organic solvents are unable to effectively address these issues. This study addressed these challenges by investigating polyethylene glycol (PEG) as a component in reactive dye ink. It was found that the PEG with longer molecular chain formed more complex coil after dissolution, which could increase ink viscosity and inhibit satellite droplets more effective. Meanwhile, the reduction of PEG concentration promoted the swelling of ink to sodium alginate (SA) film. High swelling degree and complex PEG coil could limit the ink spreading and penetration. Solid state PEG further restricted the ink spreading and penetration during the dye fixation process. Ink prepared by 3.2 wt% PEG20000 achieved no satellite droplets, the smallest spreading area and lowest permeability, and the highest dye fixation rate. Compared to commercial (CI) ink, it was evident that PEG20000/Red 218 ink exhibited less spreading and penetration, and had a higher dye fixation rate. This study introduces a promising approach for the production of high-quality, cost-effective reactive dye inks using the coil structure of polymer after dissolution.

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采用低浓度聚乙二醇调节油墨的微观结构,提高棉织物的印花质量
卫星液滴、油墨过度扩散和渗透是阻碍棉织物喷墨印刷进步的重要因素。传统的使用有机溶剂的油墨制备方法无法有效地解决这些问题。本研究通过研究聚乙二醇(PEG)作为活性染料油墨的成分来解决这些挑战。发现分子链较长的聚乙二醇溶解后形成更复杂的线圈,可以更有效地增加油墨粘度,抑制卫星液滴。同时,PEG浓度的降低促进了油墨对海藻酸钠(SA)膜的溶胀。过高的膨胀度和复杂的PEG线圈会限制油墨的扩散和渗透。固色过程中,固态聚乙二醇进一步限制了油墨的扩散和渗透。3.2% wt% PEG20000制备的油墨无卫星液滴,铺展面积最小,渗透率最低,固染率最高。与商用(CI)油墨相比,PEG20000/Red 218油墨明显具有更小的铺展和穿透性,并且具有更高的固染率。本研究介绍了一种利用聚合物溶解后的线圈结构生产高质量、低成本的活性染料油墨的方法。
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来源期刊
Cellulose
Cellulose 工程技术-材料科学:纺织
CiteScore
10.10
自引率
10.50%
发文量
580
审稿时长
3-8 weeks
期刊介绍: Cellulose is an international journal devoted to the dissemination of research and scientific and technological progress in the field of cellulose and related naturally occurring polymers. The journal is concerned with the pure and applied science of cellulose and related materials, and also with the development of relevant new technologies. This includes the chemistry, biochemistry, physics and materials science of cellulose and its sources, including wood and other biomass resources, and their derivatives. Coverage extends to the conversion of these polymers and resources into manufactured goods, such as pulp, paper, textiles, and manufactured as well natural fibers, and to the chemistry of materials used in their processing. Cellulose publishes review articles, research papers, and technical notes.
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