Wei Liu, Junjun Sun, Wei Yao, Vladimir P. Fedin, Enjun Gao
{"title":"Preparation and Properties of Cd/Ni Complexes Based on 2,6-Bis(4′-carboxyl-phenyl)pyrazine Ligand","authors":"Wei Liu, Junjun Sun, Wei Yao, Vladimir P. Fedin, Enjun Gao","doi":"10.1002/aoc.70051","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>Two transition metal complexes (complex <b>1</b> = {[Cd (DCPP)·(H<sub>2</sub>O)]·(DMF)}<sub>n</sub> and complex <b>2</b> = {[Ni (DCPP)·(H<sub>2</sub>O)]·(DMF)}<sub>n</sub>) with the same structure and different functions were synthesized based on 2,6-bis(4′-carboxybenzene)pyrazine ligand (H<sub>2</sub>DCPP) by solvothermal method, and their structure and properties were analyzed and characterized by a variety of characterization methods. Complex <b>1</b> was used as a fluorescence sensor to recognize cations and anions in water; it had excellent recognition and anti-interference ability with Fe<sup>3+</sup> and Cr<sub>2</sub>O<sub>7</sub><sup>2−</sup> among cations and anions. Complex <b>2</b> (<b>2</b>-CPE) was used as electrochemical material to perform electrochemical tests on hydrogen peroxide and sodium nitrite with good electrocatalytic effect. This work provides a synthesis strategy for fluorescence and electrochemical sensing materials, respectively.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 3","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70051","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
Two transition metal complexes (complex 1 = {[Cd (DCPP)·(H2O)]·(DMF)}n and complex 2 = {[Ni (DCPP)·(H2O)]·(DMF)}n) with the same structure and different functions were synthesized based on 2,6-bis(4′-carboxybenzene)pyrazine ligand (H2DCPP) by solvothermal method, and their structure and properties were analyzed and characterized by a variety of characterization methods. Complex 1 was used as a fluorescence sensor to recognize cations and anions in water; it had excellent recognition and anti-interference ability with Fe3+ and Cr2O72− among cations and anions. Complex 2 (2-CPE) was used as electrochemical material to perform electrochemical tests on hydrogen peroxide and sodium nitrite with good electrocatalytic effect. This work provides a synthesis strategy for fluorescence and electrochemical sensing materials, respectively.
期刊介绍：
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
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