“High-throughput LC-MS/MS discrimination of musts and wines contaminated by fresh mushroom off-flavor on the basis of reliable and easily quantifiable analytical markers: 1-hydroxyoctan-3-one and its derivate octane-1,3-diol”

IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Food Chemistry Pub Date : 2025-08-01 Epub Date: 2025-02-17 DOI:10.1016/j.foodchem.2025.143454
Sarah Ployon , Lucas Suc , Christine Le Guernevé , Eléonore Augès , Héloïse Mahé , Marion Hervé , Audrey Bloem , Aurélie Roland
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Abstract

Since the 2000's, the development of fresh mushroom off-flavor (FMOff) in wines has been a recurring problem stemming from fungal alteration on grapes. Known mushroom flavors like 1-octen-3-one do not fully explain this defect appearance during winemaking. This study aimed to identify relevant analytical markers in musts and wines to early classify the quality of these oenological matrices. Musts made with grapes naturally affected by grey mold as an apparent alteration and their corresponding wines were analyzed by LC-MS/MS. Two compounds were identified and correlated well with the development of FMOff in wines: 1-hydroxyoctan-3-one and octane-1,3-diol. The latter was identified for the first time in oenological matrices and could be derived from 1-hydroxyoctan-3-one through yeast metabolism. Both markers enabled the formal discrimination of musts with FMOff potential and FMOff wines from control samples. This provides a fast and reliable diagnostic tool for winemakers.
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基于可靠且易于定量的1-羟基辛烷-3- 1及其衍生物辛烷-1,3-二醇的高通量LC-MS/MS鉴别鲜菇味污染的葡萄酒和葡萄酒
自2000年代以来,由于真菌对葡萄的影响,葡萄酒中鲜菇异味的产生一直是一个反复出现的问题。已知的蘑菇风味,如1-辛烯-3- 1,并不能完全解释这种在酿酒过程中出现的缺陷。本研究旨在鉴别酒糟和葡萄酒中相关的分析标记物,以便对这些酿酒基质的质量进行早期分类。采用LC-MS/MS对受灰霉病影响的葡萄酿制的葡萄酒及其相应的葡萄酒进行了分析。鉴定出两种化合物:1-羟基辛烷-3- 1和辛烷-1,3-二醇,它们与葡萄酒中FMOff的形成有良好的相关性。后者是首次在酿酒基质中鉴定出来的,可以通过酵母代谢从1-羟基辛烷-3- 1中提取。这两种标记都可以正式区分具有FMOff潜力的葡萄酒和来自对照样品的FMOff葡萄酒。这为酿酒师提供了一个快速可靠的诊断工具。
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来源期刊
Food Chemistry
Food Chemistry 工程技术-食品科技
CiteScore
16.30
自引率
10.20%
发文量
3130
审稿时长
122 days
期刊介绍: Food Chemistry publishes original research papers dealing with the advancement of the chemistry and biochemistry of foods or the analytical methods/ approach used. All papers should focus on the novelty of the research carried out.
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