Meng Cao , Yewei Zhang , Mingyu Liu , Xuefeng Sun , Shuo Wang , Jian Zang
{"title":"A novel synergistic approach to improve the interfacial and mechanical properties of CF/PEEK-Ti laminates through GNPs","authors":"Meng Cao , Yewei Zhang , Mingyu Liu , Xuefeng Sun , Shuo Wang , Jian Zang","doi":"10.1016/j.tws.2025.113090","DOIUrl":null,"url":null,"abstract":"<div><div>The insufficient bond strength at the fiber/metal interface of fiber metal laminates (FMLs) is a primary obstacle to their widespread application. To address this issue, a strategy is proposed to introduce graphene nanoplatelets (GNPs) to enhance the bond strength at the carbon fiber/polyether ether ketone (CF/PEEK)-titanium interface. This approach comprises two main components. First, GNPs were deposited onto the surface of the titanium layer to form a micro-nanolayer using electrophoretic deposition (EPD). The effects of varying voltages, deposition times, and GNPs concentrations on the EPD results were investigated. Second, the PEEK matrix was modified with GNPs to further enhance the interfacial bond strength of CF/PEEK-titanium. The results indicated that optimal EPD parameters-30 V, 90 s, and a GNP concentration of 0.75 mg/mL-yielded the best outcomes. Under these conditions, the flexural strength, interfacial shear strength, and shear adhesion strength of FMLs improved by 201.9 %, 133.9 %, and 91.4 %, respectively, compared to unmodified FMLs. When combining GNPs-modified PEEK with EPD, these properties increased further, with flexural strength, interfacial shear strength, and shear adhesion strength enhanced by 281.7 %, 238.7 %, and 112.4 %, respectively, compared to unmodified FMLs. Molecular dynamics simulations were performed to further investigate the role and mechanism of GNPs in the GNPs/PEEK/titanium ternary system. The simulations revealed that combining a GNPs-modified matrix with EPD significantly enhances the system's interfacial energy. Moreover, GNPs substantially influence the torsional behaviour of the PEEK main chain. These combined experimental and simulation results offer new insights into applying GNPs in composite materials.</div></div>","PeriodicalId":49435,"journal":{"name":"Thin-Walled Structures","volume":"211 ","pages":"Article 113090"},"PeriodicalIF":6.6000,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Thin-Walled Structures","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0263823125001843","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CIVIL","Score":null,"Total":0}
引用次数: 0
Abstract
The insufficient bond strength at the fiber/metal interface of fiber metal laminates (FMLs) is a primary obstacle to their widespread application. To address this issue, a strategy is proposed to introduce graphene nanoplatelets (GNPs) to enhance the bond strength at the carbon fiber/polyether ether ketone (CF/PEEK)-titanium interface. This approach comprises two main components. First, GNPs were deposited onto the surface of the titanium layer to form a micro-nanolayer using electrophoretic deposition (EPD). The effects of varying voltages, deposition times, and GNPs concentrations on the EPD results were investigated. Second, the PEEK matrix was modified with GNPs to further enhance the interfacial bond strength of CF/PEEK-titanium. The results indicated that optimal EPD parameters-30 V, 90 s, and a GNP concentration of 0.75 mg/mL-yielded the best outcomes. Under these conditions, the flexural strength, interfacial shear strength, and shear adhesion strength of FMLs improved by 201.9 %, 133.9 %, and 91.4 %, respectively, compared to unmodified FMLs. When combining GNPs-modified PEEK with EPD, these properties increased further, with flexural strength, interfacial shear strength, and shear adhesion strength enhanced by 281.7 %, 238.7 %, and 112.4 %, respectively, compared to unmodified FMLs. Molecular dynamics simulations were performed to further investigate the role and mechanism of GNPs in the GNPs/PEEK/titanium ternary system. The simulations revealed that combining a GNPs-modified matrix with EPD significantly enhances the system's interfacial energy. Moreover, GNPs substantially influence the torsional behaviour of the PEEK main chain. These combined experimental and simulation results offer new insights into applying GNPs in composite materials.
期刊介绍：
Thin-walled structures comprises an important and growing proportion of engineering construction with areas of application becoming increasingly diverse, ranging from aircraft, bridges, ships and oil rigs to storage vessels, industrial buildings and warehouses.
Many factors, including cost and weight economy, new materials and processes and the growth of powerful methods of analysis have contributed to this growth, and led to the need for a journal which concentrates specifically on structures in which problems arise due to the thinness of the walls. This field includes cold– formed sections, plate and shell structures, reinforced plastics structures and aluminium structures, and is of importance in many branches of engineering.
The primary criterion for consideration of papers in Thin–Walled Structures is that they must be concerned with thin–walled structures or the basic problems inherent in thin–walled structures. Provided this criterion is satisfied no restriction is placed on the type of construction, material or field of application. Papers on theory, experiment, design, etc., are published and it is expected that many papers will contain aspects of all three.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
