{"title":"Conversion of CO2 into Porous Metal-Organic Framework Monoliths","authors":"Kanchana Sotho, Kentaro Kadota, Takuya Kurihara, Thanakorn Tiyawarakul, Hiroki Yamada, Kanokwan Kongpatpanich, Satoshi Horike","doi":"10.1039/d4ta08744e","DOIUrl":null,"url":null,"abstract":"We demonstrate one-pot conversion of CO<small><sub>2</sub></small> into amorphous formate-based metal-organic frameworks (MOFs) that form grain-boundary-free monoliths with permanent porosity through hot-pressing. The local coordination geometries of metal ions are characterized using solid-state NMR and synchrotron total X-ray scattering analyses. Hot-pressing decreases the pore sizes of monoliths, enhancing the adsorption selective toward H<small><sub>2</sub></small>. The key for the formation of microporous monolith is the coordination network in which formate, capable of adopting various coordination modes, is connected via stable metal–oxygen bonds.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"13 1","pages":""},"PeriodicalIF":10.7000,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry A","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d4ta08744e","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
We demonstrate one-pot conversion of CO2 into amorphous formate-based metal-organic frameworks (MOFs) that form grain-boundary-free monoliths with permanent porosity through hot-pressing. The local coordination geometries of metal ions are characterized using solid-state NMR and synchrotron total X-ray scattering analyses. Hot-pressing decreases the pore sizes of monoliths, enhancing the adsorption selective toward H2. The key for the formation of microporous monolith is the coordination network in which formate, capable of adopting various coordination modes, is connected via stable metal–oxygen bonds.
期刊介绍：
The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
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