Borna Saeednia, Aria M. Sragow, Yannan Lin, Colton J. Sheehan, Amy S. Metlay, Michael R. Gau, Samantha A. Dye, Sarah P. O'Konski, Thomas E. Mallouk, Ivan J. Dmochowski
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引用次数: 0
Abstract
We report two Cu(I)-tren host molecules with unusual air-stability, as revealed by strong preference for axial CO binding over bent O2. Spectroscopy, electrochemical, and X-ray crystal structure analyses indicate that the phenyl rotators of the capsule select for small axial ligands.
期刊介绍：
Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.
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