Preparation and functional characteristics of starch-lipid complexes with different oleic acid-rich glycerolipids

IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Food Chemistry Pub Date : 2025-06-01 Epub Date: 2025-02-18 DOI:10.1016/j.foodchem.2025.143450
Huijing Chen , Shanliang Zhong , Guoxiang Chi , Huiying Li , Kewei Chen , Zhirong Wang , Jianquan Kan
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Abstract

Starch–lipid complexes with functional properties have gained extensive attention; however, little attention has been paid to how oleic acid-based lipid types and thermomechanical treatment affect the functional characteristics of starch. This study investigated the effects of five oleic acid-based lipids (oleic acid, monoolein, diolein, triolein, and rapeseed oil) and thermomechanical treatment on the structural and physicochemical properties of wheat starch. The crystal patterns and complexing indices showed that thermomechanical treatment promoted the formation of oleic acid, monoolein, and diolein V-type starch–lipid complexes with an intact granular structure, whereas triolein and rapeseed oil formed complexes with starch. Moreover, oleic acid, monoolein, and diolein significantly altered starch gelatinisation, retrogradation behaviour, more resistant starch formed in their complexes and thus decreased its digestibility. Rheological analyses indicated that the formation of lipid complexes increased the viscoelastic modulus of starch. Our results deepen understanding of the key role of oleic acid-rich lipids in starch-based foods.

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不同富油酸甘油脂淀粉-脂复合物的制备及其功能特性
具有功能特性的淀粉-脂复合物得到了广泛的关注;然而,油酸基脂质类型和热机械处理对淀粉功能特性的影响却很少受到关注。研究了五种油酸基脂类(油酸、单油酸、二油酸、三油酸和菜籽油)和热处理对小麦淀粉结构和理化性质的影响。晶体形态和络合指标表明,热处理促进油酸、单油酸和二油酸形成完整颗粒结构的v型淀粉-脂配合物,而三油酸和菜籽油与淀粉形成配合物。此外,油酸、单油酸和二油酸显著改变了淀粉的糊化和降解行为,在它们的复合物中形成了更多的抗性淀粉,并降低了淀粉的消化率。流变学分析表明,脂质复合物的形成增加了淀粉的粘弹性模量。我们的研究结果加深了对富含油酸的脂质在淀粉类食品中的作用的理解。
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文献相关原料
公司名称
产品信息
阿拉丁
Triolein
阿拉丁
Diolein
阿拉丁
Monoolein
阿拉丁
Oleic acid
来源期刊
Food Chemistry
Food Chemistry 工程技术-食品科技
CiteScore
16.30
自引率
10.20%
发文量
3130
审稿时长
122 days
期刊介绍: Food Chemistry publishes original research papers dealing with the advancement of the chemistry and biochemistry of foods or the analytical methods/ approach used. All papers should focus on the novelty of the research carried out.
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