Assessing Hydrogen Leakage in Underground Hydrogen Storage: Insights from Parametric Analysis

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS Energy & Fuels Pub Date : 2025-02-07 DOI:10.1021/acs.energyfuels.4c05518
Milad Hashemi, Behnam Sedaee* and Yousef Fathi, 
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Abstract

Hydrogen plays a vital role in renewable energy systems and has a significant environmental impact. Storing hydrogen in underground geological formations offers an efficient and safe solution to balance production and consumption. However, due to hydrogen’s unique properties, there is a risk of leakage through the caprock of underground aquifers, potentially causing serious issues such as groundwater contamination, reduced storage efficiency, and explosion hazards. This study employs numerical simulations to investigate hydrogen leakage from caprock during underground storage, focusing on key parameters. These parameters include injection and production rates, cycle duration, hydrogen molecular diffusion, aquifer pressure, injection and production depths, well types, aquifer dip angle, caprock permeability, and capillary entry pressure. By examining these factors, the study provides an in-depth comprehensive analysis of hydrogen leakage from aquifers, addressing a critical gap in existing research. The results indicate that a significant amount of the total injected hydrogen leaks into the caprock after eight years of injection and storage cycles. This leakage can have significant environmental and economic impacts. The study also reveals that caprock permeability is crucial in influencing hydrogen leakage with higher permeability leading to increased leakage rates. Moreover, vertical caprock permeability has a more pronounced effect on leakage rates than horizontal permeability. Additionally, factors such as aquifer pressure, aquifer dip angle, injection and production depths, and hydrogen injection duration contribute to a higher hydrogen leakage from the caprock. The findings underscore the importance of carefully selecting underground hydrogen storage sites to mitigate the potential risks of hydrogen leakage.

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地下储氢库氢泄漏评估:参数分析的启示
氢在可再生能源系统中起着至关重要的作用,并对环境产生重大影响。在地下地质构造中储存氢气为平衡生产和消费提供了有效和安全的解决方案。然而,由于氢气的独特性质,存在通过地下含水层盖层泄漏的风险,可能导致地下水污染、储存效率降低和爆炸危险等严重问题。本文采用数值模拟的方法对地下储氢过程中盖层的氢气泄漏进行了研究,重点研究了关键参数。这些参数包括注采速度、循环时间、氢分子扩散、含水层压力、注采深度、井型、含水层倾角、盖层渗透率和毛管进入压力。通过考察这些因素,该研究对含水层氢泄漏进行了深入全面的分析,解决了现有研究中的一个关键空白。结果表明,经过8年的注入和储存周期,大量注入的氢气泄漏到盖层中。这种泄漏会对环境和经济造成重大影响。研究还表明,盖层渗透率是影响氢泄漏的关键因素,渗透率越高,泄漏率越高。此外,垂向盖层渗透率对泄漏速率的影响比水平渗透率更显著。此外,含水层压力、含水层倾角、注入和生产深度、注氢时间等因素也导致了盖层氢气泄漏的增加。研究结果强调了仔细选择地下储氢地点以减轻氢气泄漏潜在风险的重要性。
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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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