Comparative Evaluation of the Effects of Long-Term and Short-Term Water–Rock Interaction on the Microstructure and Mechanical Properties of Shale

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS Energy & Fuels Pub Date : 2025-02-11 DOI:10.1021/acs.energyfuels.4c06122
Changliang Wu, Hongjian Zhu*, Yanjun Lu*, Deng Zhao, Jun Chu and Yu Qi, 
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Abstract

Accurately determining the stability of shale gas reservoirs requires an understanding of the mechanical behavior and microstructural changes exposed to both short-term and long-term water–rock interactions during hydraulic fracturing. After soaking Longmaxi shales in slick water for 0, 5, 15, 30, 60, 120, and 180 days, we use laboratory uniaxial and triaxial compression experiments across TPc (high temperature and high pressure) conditions to examine these changes. The results indicate significant differences in the effects of long-term versus short-term water–rock interaction on the mechanical properties of shale. Furthermore, as the duration of water–rock interaction increases, the correlation among mechanical properties, brittle mineral content, and various fractal dimensions gradually diminishes, especially after immersion exceeding 15 days. In contrast, the correlation between surface roughness, pore structure, and shale mechanical properties remains consistently stable, with surface roughness being particularly notable. Based on surface roughness, we propose a multiscale quantitative characterization method for rock damage using the analytical hierarchy process (AHP) calculation method, grounded in fractal damage mechanics theory (covering macroscopic and mesoscopic scales). Consequently, a shale damage evolution model under water–rock interaction is formulated, which can predict and assess the degree of damage in shale gas reservoirs following different durations of water–rock interaction. In addition, we propose the mechanisms to demonstrate how the microstructure and mechanical behavior of shale vary depending on the duration of the water–rock interaction: (1) surface hydration and ionic hydration (mineral dissolution and detachment, ion exchange), predominantly occurring under conditions of short-term water–rock interaction, and (2) osmotic hydration (pore pressure fluctuations, alterations in stress distribution, crack propagation, and clay swelling), which typically takes place over a longer duration and is primarily observed in long-term water–rock interaction scenarios.

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长期和短期水岩相互作用对页岩微观结构和力学性能影响的对比评价
要准确确定页岩气储层的稳定性,需要了解水力压裂过程中水岩短期和长期相互作用下的力学行为和微观结构变化。在将龙马溪页岩浸泡于滑水中0、5、15、30、60、120和180天后,我们采用高温高压条件下的单轴和三轴压缩实验来观察这些变化。结果表明,长期和短期水岩相互作用对页岩力学特性的影响存在显著差异。随着水岩相互作用时间的延长,岩石力学性能、脆性矿物含量与各分形维数之间的相关性逐渐减弱,特别是浸泡时间超过15 d后。相比之下,表面粗糙度、孔隙结构和页岩力学性质之间的相关性保持稳定,其中表面粗糙度尤为显著。基于表面粗糙度,基于分形损伤力学理论(涵盖宏观和细观尺度),提出了一种基于层次分析法(AHP)的岩石损伤多尺度定量表征方法。在此基础上,建立了水岩相互作用下的页岩损伤演化模型,用于预测和评价不同水岩相互作用时间下页岩气藏的损伤程度。此外,我们提出了一些机制来证明页岩的微观结构和力学行为是如何随着水岩相互作用的持续时间而变化的:(1)表面水化和离子水化(矿物溶解和分离、离子交换),主要发生在短期水岩相互作用条件下;(2)渗透水化(孔隙压力波动、应力分布变化、裂纹扩展和粘土膨胀),通常持续时间较长,主要发生在长期水岩相互作用条件下。
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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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