Kayla M Fugami, Gabriel S Black, Tim Kowalczyk, Takele Seda, John D Gilbertson
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引用次数: 0
Abstract
The intermolecular N-N coupling of NO in a dinitrosyl iron complex (DNIC) induced by hydrogen bond donors in the secondary coordination sphere to form N2O is reported. A family of complexes containing pendant anilines in the secondary coordination sphere were synthesized and characterized. Reduction of the {Fe(NO)2}9 complex [Fe(PhNHPDI)(NO)2][BPh4] (3) to the {Fe(NO)2}10 Fe(PhNHPDI)(NO)2 (4) results in intermolecular N-N coupling to form N2O. Similar reactions of the control {Fe(NO)2}9 complex [Fe(PhNMePDI)(NO)2][BPh4] (7), which does not have H-bonding groups in the secondary coordination sphere, do not result in N2O formation. The hydrogen bonding capabilities of the complexes were explored spectroscopically and computationally.
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The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.
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