Andrea Ninarello, Jérôme J. Crassous, Divya Paloli, Fabrizio Camerin, Nicoletta Gnan, Lorenzo Rovigatti, Peter Schurtenberger, Emanuela Zaccarelli
{"title":"Correction to “Modeling Microgels with a Controlled Structure across the Volume Phase Transition”","authors":"Andrea Ninarello, Jérôme J. Crassous, Divya Paloli, Fabrizio Camerin, Nicoletta Gnan, Lorenzo Rovigatti, Peter Schurtenberger, Emanuela Zaccarelli","doi":"10.1021/acs.macromol.5c00336","DOIUrl":null,"url":null,"abstract":"The bottom panel of Figure 2e displays an incorrect cross-linker density profile, derived from averaging together incorrect topologies. The corrected profile is given Figure 2e below. As a consequence, the final sentence of the paragraph “<i>The Choice of the Designing Force</i>” should be revised from \"<i>Interestingly, in this case, the cross-linker profile is continuously decreasing from the center of the microgel and does not reflect the total profile of all monomers.\"</i> to <i>\"In this case, the cross-linker profile follows the core-corona structure of the total profile of all monomers\".</i> Figure 2. (e) Density profiles for all particles (symbols) and for cross-linkers only (dashed lines). Inward forces acting only on cross-linkers is considered as in eq 5 of the main paper with <i>g</i> = 8 × 10<sup>–3</sup> and <i>k</i> = 4.5 × 10<sup>–5</sup>. The integral of ρ(<i>r</i>) is normalized to a constant value ∫ρ(<i>r</i>) d<i>r</i> = <i>n</i> with <i>n</i> = 10, 5 for all particles and cross-linkers, respectively, to improve visualization. Data are averaged over four independent realizations obtained with the numerical protocol described in the Models and Methods section of the main paper. This article has not yet been cited by other publications.","PeriodicalId":51,"journal":{"name":"Macromolecules","volume":"89 1","pages":""},"PeriodicalIF":5.1000,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecules","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.macromol.5c00336","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
The bottom panel of Figure 2e displays an incorrect cross-linker density profile, derived from averaging together incorrect topologies. The corrected profile is given Figure 2e below. As a consequence, the final sentence of the paragraph “The Choice of the Designing Force” should be revised from "Interestingly, in this case, the cross-linker profile is continuously decreasing from the center of the microgel and does not reflect the total profile of all monomers." to "In this case, the cross-linker profile follows the core-corona structure of the total profile of all monomers". Figure 2. (e) Density profiles for all particles (symbols) and for cross-linkers only (dashed lines). Inward forces acting only on cross-linkers is considered as in eq 5 of the main paper with g = 8 × 10–3 and k = 4.5 × 10–5. The integral of ρ(r) is normalized to a constant value ∫ρ(r) dr = n with n = 10, 5 for all particles and cross-linkers, respectively, to improve visualization. Data are averaged over four independent realizations obtained with the numerical protocol described in the Models and Methods section of the main paper. This article has not yet been cited by other publications.
期刊介绍:
Macromolecules publishes original, fundamental, and impactful research on all aspects of polymer science. Topics of interest include synthesis (e.g., controlled polymerizations, polymerization catalysis, post polymerization modification, new monomer structures and polymer architectures, and polymerization mechanisms/kinetics analysis); phase behavior, thermodynamics, dynamic, and ordering/disordering phenomena (e.g., self-assembly, gelation, crystallization, solution/melt/solid-state characteristics); structure and properties (e.g., mechanical and rheological properties, surface/interfacial characteristics, electronic and transport properties); new state of the art characterization (e.g., spectroscopy, scattering, microscopy, rheology), simulation (e.g., Monte Carlo, molecular dynamics, multi-scale/coarse-grained modeling), and theoretical methods. Renewable/sustainable polymers, polymer networks, responsive polymers, electro-, magneto- and opto-active macromolecules, inorganic polymers, charge-transporting polymers (ion-containing, semiconducting, and conducting), nanostructured polymers, and polymer composites are also of interest. Typical papers published in Macromolecules showcase important and innovative concepts, experimental methods/observations, and theoretical/computational approaches that demonstrate a fundamental advance in the understanding of polymers.