Enhancement of high-temperature solar-blind UV photodetector performance on 4H–SiC substrates by deposition of ultrawide bandgap diamond films

IF 11.6 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Carbon Pub Date : 2025-02-19 DOI:10.1016/j.carbon.2025.120130
Ming Huang , Bing Yang , Ge Xu , Jiaqi Lu , Yubin Guo , Lingyue Weng , Dongming Sun
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Abstract

High-temperature operation and solar-blind ultraviolet (UV) sensitivity remain significant challenges for 4H–SiC-based photodetectors, limiting their performance in harsh environmental conditions. To address these issues, the deposition of ultrawide bandgap diamond films is employed to enhance the high-temperature performance of solar-blind UV photodetectors. Diamond films of varying thicknesses were deposited on 4H–SiC substrates using microwave plasma chemical vapor deposition. The photodetector achieves a maximum room-temperature responsivity of 0.12 A/W under 220 nm illumination with a 15 V bias, nearly 15 times higher than that observed in a 4H–SiC-only photodetector. Furthermore, the photodetectors exhibit exceptional UV/visible rejection ratios of 645, a photo-to-dark current ratio of 5.34 × 103, and a detectivity of 2.55 × 1012 Jones at room temperature. As the operating temperature increases, both the 220 nm responsivity and UV/visible rejection ratio improve, reaching approximately 0.6 A/W and 980 at 200 °C, respectively, which are 30 and 245 times higher than those of the pure SiC photodetector. The diamond films significantly enhance the solar-blind UV performance of SiC-based photodetectors at high temperatures.

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在4H-SiC衬底上沉积超宽禁带金刚石膜增强高温日盲UV光电探测器性能
高温操作和太阳盲紫外(UV)灵敏度仍然是4h - sic基光电探测器面临的重大挑战,限制了它们在恶劣环境条件下的性能。为了解决这些问题,采用超宽带隙金刚石薄膜的沉积来提高太阳盲紫外光电探测器的高温性能。采用微波等离子体化学气相沉积技术在4H-SiC衬底上沉积了不同厚度的金刚石薄膜。该光电探测器在220 nm照明和15 V偏置下的最大室温响应率为0.12 a /W,比纯4h - sic光电探测器高近15倍。此外,光电探测器在室温下的UV/可见光抑制比为645,光暗电流比为5.34 × 103,探测率为2.55 × 1012琼斯。随着工作温度的升高,220 nm的响应率和UV/可见光抑制比均有所提高,在200℃时分别达到约0.6 A/W和980,分别是纯SiC光电探测器的30倍和245倍。金刚石薄膜显著提高了硅基光电探测器在高温下的日盲紫外性能。
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来源期刊
Carbon
Carbon 工程技术-材料科学:综合
CiteScore
20.80
自引率
7.30%
发文量
0
审稿时长
23 days
期刊介绍: The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.
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