The impact of TeO2 content on radiation shielding properties for zinc-tellurite borosilicate glasses

IF 1.8 3区 工程技术 Q3 CHEMISTRY, INORGANIC & NUCLEAR Applied Radiation and Isotopes Pub Date : 2025-02-18 DOI:10.1016/j.apradiso.2025.111742
A.S. Mostafa , M.M. Kassab , M.M. Radwan , Ahmed M. Al Kaisy , A. Abdel-Latif M
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Abstract

A novel Zinc-Tellurite borosilicate (ZTBS) glass system was successfully synthesized via the melt quench process. Its chemical composition is represented by the formula (44SiO2-25B2O3-18Na2O-6CaO-1ZrO2-(6-x)ZnO-xTeO2), and its weight fraction (x = 0, 2, 4, 6 wt%). The shielding properties, there is perfect agreement between the results of the theoretical calculation of the mass attenuation coefficient using the Phy-X/PSD and the compatible values derived from the WinXCom databases. Further, several photon shielding parameters were computed in the 15 keV–15 MeV energy range, including the mass attenuation coefficient (MAC), half value layer (HVL), mean free path (MFP), exposure buildup factor (EBF), and effective atomic number (Zeff). The preferred sample for gamma ray shielding is the sample with the highest TeO2 concentration (ZTBS3), according to the results. ZTBS3 glass samples have greater MAC and HVL values than other published borosilicate glasses at 662.61 k eV photon energy which reaches 0.07626 cm−2/g and 3.429 cm respectively. Also, LAC values is higher in the sample with the largest concentration of TeO2. Furthermore, the computed HVL and MFP were lower than those of regular concrete. The shielding results indicate that the newly developed transparent ZTBS glasses compositions that are lightweight and have good shielding properties that may be suitable in shielding applications. Depending on the application, the ratio of TeO2 additive should be balanced between improved shielding and glass stability features.

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TeO2 含量对锌碲硼硅玻璃辐射屏蔽性能的影响
采用熔融淬火工艺成功合成了新型的锌-碲硼硅酸盐(ZTBS)玻璃体系。其化学组成为(44sio2 - 25b2o3 - 18na20 - 6cao - 1zro2 -(6-x)ZnO-xTeO2),其质量分数为(x = 0,2,4,6 wt%)。在屏蔽性能方面,采用Phy-X/PSD计算的质量衰减系数的理论计算结果与WinXCom数据库的兼容值吻合较好。在15kv - 15mev能量范围内计算了光子屏蔽参数,包括质量衰减系数(MAC)、半值层(HVL)、平均自由程(MFP)、暴露累积因子(EBF)和有效原子序数(Zeff)。结果表明,屏蔽γ射线的首选样品是TeO2浓度最高的样品(ZTBS3)。在光子能量为662.61 k eV时,ZTBS3玻璃样品的MAC和HVL值分别达到0.07626 cm−2/g和3.429 cm,高于其他已发表的硼硅酸盐玻璃样品。同时,在TeO2浓度最大的样品中LAC值也较高。计算得到的HVL和MFP均低于普通混凝土。屏蔽结果表明,新研制的透明ZTBS玻璃组合物重量轻,具有良好的屏蔽性能,可用于屏蔽应用。根据不同的应用,TeO2添加剂的比例应在提高屏蔽性能和玻璃稳定性之间取得平衡。
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来源期刊
Applied Radiation and Isotopes
Applied Radiation and Isotopes 工程技术-核科学技术
CiteScore
3.00
自引率
12.50%
发文量
406
审稿时长
13.5 months
期刊介绍: Applied Radiation and Isotopes provides a high quality medium for the publication of substantial, original and scientific and technological papers on the development and peaceful application of nuclear, radiation and radionuclide techniques in chemistry, physics, biochemistry, biology, medicine, security, engineering and in the earth, planetary and environmental sciences, all including dosimetry. Nuclear techniques are defined in the broadest sense and both experimental and theoretical papers are welcome. They include the development and use of α- and β-particles, X-rays and γ-rays, neutrons and other nuclear particles and radiations from all sources, including radionuclides, synchrotron sources, cyclotrons and reactors and from the natural environment. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. Papers dealing with radiation processing, i.e., where radiation is used to bring about a biological, chemical or physical change in a material, should be directed to our sister journal Radiation Physics and Chemistry.
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