Radical Chain Oxidation of Methyl Oleate as a Model System for Studying the Activity and Concentration of Antioxidants in Evening Primrose Oil and Borage Seed Oil

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL Kinetics and Catalysis Pub Date : 2025-02-25 DOI:10.1134/S0023158424602419
L. R. Yakupova, R. L. Safiullin
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Abstract

A model reaction of radical chain oxidation of methyl oleate was used to study natural compounds for antioxidant activity. Secondary peroxyl radicals were generated by controlled initiated lipid oxidation. The system was used to evaluate the antioxidant activity of natural oils obtained by extracting crushed seeds of the medicinal plants evening primrose and borage. The effective rate constant of methyl oleate peroxyl radicals with inhibitors contained in the oils was measured. The concentration of antioxidants was found and the qualitative composition of the antioxidants was suggested.

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油酸甲酯自由基链氧化作为研究月见草油和琉璃苣籽油抗氧化剂活性和浓度的模型体系
采用油酸甲酯自由基链氧化模型反应研究了天然化合物的抗氧化活性。次生过氧自由基是由受控的脂质氧化引起的。利用该体系对药用植物月见草和琉璃苣种子碾碎提取的天然油脂进行抗氧化活性评价。测定了油酸甲酯过氧自由基在抑制剂作用下的有效速率常数。测定了抗氧化剂的浓度,并提出了抗氧化剂的定性组成。
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来源期刊
Kinetics and Catalysis
Kinetics and Catalysis 化学-物理化学
CiteScore
2.10
自引率
27.30%
发文量
64
审稿时长
6-12 weeks
期刊介绍: Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.
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