Plurality of Luminophores of Super-Bright Carbon Dots Synthesized from Citric Acid and Ethylenediamine

IF 0.48 Q4 Physics and Astronomy Bulletin of the Russian Academy of Sciences: Physics Pub Date : 2025-02-25 DOI:10.1134/S1062873824708924
A. M. Vervald, K. A. Laptinskiy, M. Yu. Khmeleva, T. A. Dolenko
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Abstract

Hydrothermal treatment of a mixture of citric acid (CA) and ethylenediamine (EDA) is known for production of carbon dots (CDs) with intense photoluminescence (PL) in the blue region with a quantum yield up to ∼95%. However, the specific result of the synthesis depends significantly on treatment’s parameters. In this manuscript, by studying CDs synthesized from an EDA : CA mixture of 1 : 1 at temperatures of 80, 140, or 200°C for 0.5–6 h, it was found that, in addition to the main PL peak with a maximum in the region of λexem 350/440 nm/nm, 6 different peaks with lower PL intensity are observed at different stages of the synthesis, corresponding to different luminophores. The parameters and conditions of formation of these luminophores were studied, the quantum yields of their luminescence obtained.

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柠檬酸和乙二胺合成多个超亮碳点发光团
众所周知,水热处理柠檬酸(CA)和乙二胺(EDA)的混合物可以在蓝色区域产生具有强光致发光(PL)的碳点(CDs),量子产率高达95%。然而,合成的具体结果在很大程度上取决于处理的参数。本文通过对以EDA: CA为1:1的混合物,在80,140,或200℃条件下合成CDs 0.5-6 h的研究,发现除了在λex/λem 350/440 nm/nm范围内最大的主发光峰外,在合成的不同阶段还观察到6个不同的发光强度较低的峰,对应于不同的发光团。研究了这些发光团的形成参数和条件,得到了它们发光的量子产率。
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来源期刊
Bulletin of the Russian Academy of Sciences: Physics
Bulletin of the Russian Academy of Sciences: Physics Physics and Astronomy-Physics and Astronomy (all)
CiteScore
0.90
自引率
0.00%
发文量
251
期刊介绍: Bulletin of the Russian Academy of Sciences: Physics is an international peer reviewed journal published with the participation of the Russian Academy of Sciences. It presents full-text articles (regular,  letters  to  the editor, reviews) with the most recent results in miscellaneous fields of physics and astronomy: nuclear physics, cosmic rays, condensed matter physics, plasma physics, optics and photonics, nanotechnologies, solar and astrophysics, physical applications in material sciences, life sciences, etc. Bulletin of the Russian Academy of Sciences: Physics  focuses on the most relevant multidisciplinary topics in natural sciences, both fundamental and applied. Manuscripts can be submitted in Russian and English languages and are subject to peer review. Accepted articles are usually combined in thematic issues on certain topics according to the journal editorial policy. Authors featured in the journal represent renowned scientific laboratories and institutes from different countries, including large international collaborations. There are globally recognized researchers among the authors: Nobel laureates and recipients of other awards, and members of national academies of sciences and international scientific societies.
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