Renewable Nanocatalyst Based on Palladium Nanoparticles Decorated on the Functionalized Metal–Organic Framework for Synthesis of Biaryl Derivatives

IF 3.7 2区化学 Q2 CHEMISTRY, APPLIED Applied Organometallic Chemistry Pub Date : 2025-02-26 DOI:10.1002/aoc.8004

Fatemeh Yazdiamiri, Heshmatollah Alinezhad, Shahram Ghasemi

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Abstract

The unique postsynthetic functionalization characteristic of metal–organic frameworks (MOF), especially those that possess a free -NH₂ group, encourages researchers to design nanocatalysts based on MOF with crystalline architecture. The present work reports a new nanocatalyst of UiO-66-NH-Glu-Mla@Pd, focusing on its design, synthesis, functionalization, and application in the Suzuki coupling reaction. UiO-66-NH₂ MOF was successfully synthesized via a solvothermal method and then functionalized with organic reagents of glutaraldehyde (Glu) and melamine (Mla) using the cocondensation and postsynthesis grafting strategies. Finally, the UiO-66-NH-Glu-Mla was decorated by palladium nanoparticles to generate UiO-66-NH-Glu-Mla@Pd. These modifications turn a low-active MOF into an ideal nanocatalyst with high catalytic activity in the Suzuki reaction. The results showed that the efficiency and durability of structure UiO-66-NH-Glu-Mla@Pd was still high after at least six consecutive uses.

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来源期刊

Applied Organometallic Chemistry 化学-无机化学与核化学

CiteScore

7.80

自引率

10.30%

发文量

408

审稿时长

2.2 months

期刊介绍： All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.