Growth rate dependence of the permeability and percolation threshold of young sea ice

IF 3.1 3区 化学 Q2 Chemistry Faraday Discussions Pub Date : 2025-01-02 DOI:10.1039/D4FD00172A
Sönke Maus
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Abstract

The permeability of sea ice is difficult to observe, and physically based permeability models are lacking so far. Here a model for the permeability of sea ice is presented that combines extensive microstructure observations and modelling with directed percolation theory. The model predicts the dependence of sea ice permeability on brine porosity and growth rate, as well as a percolation transition to impermeable sea ice due to necking of the pores. It is validated by numerical simulations of sea ice permeability on 3D images from X-ray microtomographic imaging and by other existing permeability data. A fundamental model result is that the percolation threshold of sea ice scales as ϕca0−1 where a0 is the plate or brine layer spacing. As the plate spacing decreases with growth velocity V, this implies that the percolation threshold increases as ϕcV1/3, with the cubic root of the growth rate. For growth rates of natural sea ice the percolation threshold is expected to be in the range of 1 to 4 percent volume fraction of brine. While developed for columnar sea ice, a simple modification for granular surface ice also agrees with observations. The model is valid for sea ice during the growth phase, prior to warming and melting. Permeability modelling of spring and summer sea ice, with wider secondary brine channels present, requires 3D pore space observations in warming sea ice that currently are sparse.

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新生海冰渗透率和渗滤阈值的生长速率依赖性。
海冰的渗透性很难观测,目前还缺乏基于物理的渗透性模型。本文提出了一个结合大量微观结构观测和定向渗透理论建模的海冰渗透率模型。该模型预测了海冰渗透率与盐水孔隙度和生长速率的关系,以及由于孔隙缩窄导致的向不透水海冰的渗透过渡。通过x射线显微层析成像三维图像的海冰渗透率数值模拟和其他现有渗透率数据验证了该方法的有效性。一个基本的模型结果是,海冰的渗透阈值为:ϕc∝a0-1,其中a0为板间距或卤水层间距。当板间距随生长速度V而减小时,则渗透阈值随生长速度的立方根而增大,即为ϕc∝V1/3。对于自然海冰的增长率,预计渗透阈值在盐水体积分数的1%至4%之间。虽然是为柱状海冰开发的,但对颗粒状表面冰的简单修正也与观测结果一致。该模型适用于海冰在升温和融化之前的生长阶段。春季和夏季海冰的渗透率建模存在更宽的二次盐水通道,需要在目前稀疏的变暖海冰中进行三维孔隙空间观测。
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来源期刊
Faraday Discussions
Faraday Discussions CHEMISTRY, PHYSICAL-
CiteScore
4.90
自引率
0.00%
发文量
259
审稿时长
2.8 months
期刊介绍: Discussion summary and research papers from discussion meetings that focus on rapidly developing areas of physical chemistry and its interfaces
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