Effects of nano- and micro-cellulose on Ca(OH)2 formation: Implications for lime-based binders

IF 10.9 1区工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Cement and Concrete Research Pub Date : 2025-02-27 DOI:10.1016/j.cemconres.2025.107851

Paulina Guzmán García Lascurain , Carlos Rodriguez-Navarro , Lucia Toniolo , Sara Goidanich

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引用次数: 0

Abstract

Air lime-based mortars and plasters are preferred for the restoration of historic masonry due to their high compatibility, and for modern constructions given their lower environmental impact. However, their slow setting (via carbonation) and their limited strength hinder their widespread use. This study explores the influence of nano- and micro-cellulose additives dosed during lime slaking on the formation and textural/structural features of calcium hydroxide. The alkaline degradation of the additives, along with their interaction and adsorption/occlusion during heterogeneous and homogeneous precipitation of calcium hydroxide was studied. Both additives foster the non-classical crystallization of portlandite via amorphous phases, resulting in plate-like crystals in the case of nano-cellulose, whereas more reactive micro-cellulose promotes the stabilization of a dense liquid precursor, and upon its dehydration, the stabilization of amorphous calcium hydroxide. Ultimately both additives lead to the formation of potentially more reactive nano and mesostructured Ca(OH)₂ particles.

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来源期刊

Cement and Concrete Research 工程技术-材料科学：综合

CiteScore

20.90

自引率

12.30%

发文量

318

审稿时长

53 days

期刊介绍： Cement and Concrete Research is dedicated to publishing top-notch research on the materials science and engineering of cement, cement composites, mortars, concrete, and related materials incorporating cement or other mineral binders. The journal prioritizes reporting significant findings in research on the properties and performance of cementitious materials. It also covers novel experimental techniques, the latest analytical and modeling methods, examination and diagnosis of actual cement and concrete structures, and the exploration of potential improvements in materials.