Bei-Lei Wang , Lin-Yuan Zeng , Pei-Zhen Qu , De-Zhi Yang
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引用次数: 0
Abstract
Polyfluoroaromatic compounds are important components in medicinal and material science, however, methodologies for the synthesis of alkylated pentafluoroarenes remains limited. Here we developed a deaminative coupling reaction of Katritzky salts with pentafluorostyrene to construct C6F5-C(sp3) bonds promoted by the photochemical activity of electron donor-acceptor (EDA) complexes. This method features simple reaction conditions, a broad substrate scope, and good functional group tolerance.
期刊介绍：
Synthetic Communications presents communications describing new methods, reagents, and other synthetic work pertaining to organic chemistry with sufficient experimental detail to permit reported reactions to be repeated by a chemist reasonably skilled in the art. In addition, the Journal features short, focused review articles discussing topics within its remit of synthetic organic chemistry.
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