Electron Attachment to Nitric Oxide (NO) Controversy.

IF 2.8 2区 化学 Q3 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry A Pub Date : 2025-03-13 Epub Date: 2025-02-28 DOI:10.1021/acs.jpca.4c07675
Ana I Lozano, Juan C Oller, Paulo Limão-Vieira, Gustavo García
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Abstract

We report novel total electron scattering cross sections (TCS) from nitric oxide (NO) in the impact energy range from 1 to 15 eV by using a magnetically confined electron transmission apparatus. The accuracy of the data to within 5% and its consistency across the energy range investigated, shows significant discrepancies from previous works as to the major resonance features and magnitude of the TCS. Within the shape of the TCS, we have identified nine features which have been assigned to electron attachment resonances, most of them reported for the first time, while a comprehensive analysis of those peaking at 7.0, 7.8, and 8.8 eV has led to solve the controversy about dissociative electron attachment (DEA) cross-section that persisted for more than 50 years.

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一氧化氮(NO)的电子附着争议。
我们利用磁约束电子透射装置,报告了一氧化氮(NO)在 1 至 15 eV 的冲击能量范围内的新型电子总散射截面(TCS)。数据的精确度在 5% 以内,并且在所研究的能量范围内保持一致,这表明在 TCS 的主要共振特征和大小方面与之前的研究存在显著差异。在TCS的形状中,我们发现了九个被归类为电子附着共振的特征,其中大部分是首次报道,而对峰值在7.0、7.8和8.8 eV的共振的全面分析,则解决了持续了50多年的关于离解电子附着(DEA)截面的争议。
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来源期刊
The Journal of Physical Chemistry A
The Journal of Physical Chemistry A 化学-物理:原子、分子和化学物理
CiteScore
5.20
自引率
10.30%
发文量
922
审稿时长
1.3 months
期刊介绍: The Journal of Physical Chemistry A is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.
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