Eduardo Laborda, Javier López-Asanza, Judit Moreno-Molina, Joaquín Gonzalez, Angela Molina
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Abstract
An analytical approach is presented for the voltammetric and chronoamperometric study of a second-order cyclic-type mechanism where two species are ‘activated’ electrochemically and subsequently react in solution, as observed in co-reactant electrochemiluminescence mechanisms. Closed-form expressions are derived for the current-potential-time response and for the surface species concentrations as a function of the chemical rate constant, the concentration ratio of the initial species, and their formal potentials. Their effects on the voltammetric signal are analyzed, pointing out a wave-splitting behaviour for fast kinetics, which is tied to the rates of formation and consumption of the ‘activated’ co-reactant.
期刊介绍：
ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.
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