Cover Feature: Ce[N(SiMe3)2]3(THF)3-Catalyzed Hydroboration of CO2, Esters and Epoxides with Pinacolborane: Selective Synthesis of Methanol in Multigram Scale (Chem. Eur. J. 13/2025)
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Abstract
The Cover Feature shows an efficient method for the selective conversion of CO2 to methanol by using a cerium(III) catalyst with HBpin under mild reaction conditions. In their Research Article (DOI: 10.1002/chem.202403449), K. Vanka, S. Khan and co-workers explain how they scaled this method to a multigram-scale synthesis of pure methanol and performed DFT studies to understand the mechanistic cycle.
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