Cover Feature: Cascade Synthesis in Water: Michael Addition/Hemiketalization/Retro-Claisen Fragmentation Catalyzed by CatAnionic Vesicular Nanoreactor from Dithiocarbamate (Chem. Asian J. 5/2025)

IF 3.3 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemistry - An Asian Journal Pub Date : 2025-03-03 DOI:10.1002/asia.202580503

Ayodele J. Atibioke, Panassilp Authai, Tirayut Vilaivan, Panuwat Padungros

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Abstract

Vesicling along Wat Arun (Temple of Dawn): Situated on the Chao Phraya River in Bangkok, the river has supported civilizations for centuries. Similarly, water proves essential as a green reaction medium. N,N-Didodecylammonium N,N-didodecyldithiocarbamate (AmDTC-C₁₂C₁₂), a CatAnionic vesicular nanoreactor, enables cascade synthesis in water. Reactions between 2-hydroxy-trans-β-nitrostyrenes and 1,3-dicarbonyls yield 4H-chromenes and γ-nitro ketones efficiently, demonstrating the potential of vesicular nanoreactor for sustainable synthesis. More details can be found in article number e202400853 by Panuwat Padungros and co-workers.

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封面特写：二硫代氨基甲酸酯在水中的级联合成：迈克尔加成/半池化/反克莱森碎裂催化的阳离子囊泡纳米反应器（化学）。亚洲J. 5/2025)

沿着黎明寺（Wat Arun）游览：位于曼谷湄南河（Chao Phraya River）上，这条河已经支撑了几个世纪的文明。同样，水被证明是必不可少的绿色反应介质。N，N-二十二烷基氨氮，N，N-二十二烷基二硫代氨基甲酸酯（AmDTC-C12C12）是一种阳离子囊状纳米反应器，可在水中进行级联合成。2-羟基反式β-硝基苯乙烯与1,3-二羰基之间的反应可有效地生成4h -铬和γ-硝基酮，证明了囊状纳米反应器具有可持续合成的潜力。更多细节可以在Panuwat Padungros及其同事的文章e202400853中找到。

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来源期刊

Chemistry - An Asian Journal 化学-化学综合

CiteScore

7.00

自引率

2.40%

发文量

535

审稿时长

1.3 months

期刊介绍： Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).