Superhydrophobic magnetic melamine sponge modified by flowerlike ZnO and stearic acid using dip coating method for oil and water separation.

IF 3.9 2区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Scientific Reports Pub Date : 2025-03-03 DOI:10.1038/s41598-025-92246-8
Mahshid Hojatjalali, Soheil Bahraminia, Mansoor Anbia
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Abstract

The increasing occurrence of oil spills and industrial effluents containing oil have heightened the need for effective oil-water separation. This study developed a magnetic superhydrophobic melamine sponge using a dip-coating method with ZnO, stearic acid, and Fe3O4 nanoparticles. Characterization via XRD, FESEM, EDX, FT-IR, AFM, VSM, and water contact angle measurements (160.96˚ ± 0.65˚) revealed its excellent properties. The sponge demonstrated a sorption capacity of 36.12 ± 1.9 to 83.71 ± 2.8 g·g-1 and separation efficiency ranging from 97.82 ± 1.3 to 99.83 ± 1.7%. Its performance in removing oil from real industrial effluent was also evaluated. Additionally, the sponge exhibited reusability and high efficiency in separating emulsified oil droplets. These results highlight the potential of the modified sponge as an effective sorbent for oily wastewater treatment.

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花状氧化锌和硬脂酸对超疏水磁性三聚氰胺海绵进行浸涂改性,用于油水分离。
石油泄漏和含油工业废水的日益增加,提高了对有效油水分离的需要。本研究采用ZnO、硬脂酸和Fe3O4纳米颗粒浸渍包膜的方法制备了磁性超疏水三聚氰胺海绵。通过XRD、FESEM、EDX、FT-IR、AFM、VSM和水接触角(160.96˚±0.65˚)测试表明其具有优异的性能。吸附量为36.12±1.9 ~ 83.71±2.8 g·g-1,分离效率为97.82±1.3 ~ 99.83±1.7%。并对其在实际工业废水中的除油性能进行了评价。此外,海绵具有可重复使用性和高效分离乳化油滴的特点。这些结果突出了改性海绵作为含油废水处理有效吸附剂的潜力。
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来源期刊
Scientific Reports
Scientific Reports Natural Science Disciplines-
CiteScore
7.50
自引率
4.30%
发文量
19567
审稿时长
3.9 months
期刊介绍: We publish original research from all areas of the natural sciences, psychology, medicine and engineering. You can learn more about what we publish by browsing our specific scientific subject areas below or explore Scientific Reports by browsing all articles and collections. Scientific Reports has a 2-year impact factor: 4.380 (2021), and is the 6th most-cited journal in the world, with more than 540,000 citations in 2020 (Clarivate Analytics, 2021). •Engineering Engineering covers all aspects of engineering, technology, and applied science. It plays a crucial role in the development of technologies to address some of the world''s biggest challenges, helping to save lives and improve the way we live. •Physical sciences Physical sciences are those academic disciplines that aim to uncover the underlying laws of nature — often written in the language of mathematics. It is a collective term for areas of study including astronomy, chemistry, materials science and physics. •Earth and environmental sciences Earth and environmental sciences cover all aspects of Earth and planetary science and broadly encompass solid Earth processes, surface and atmospheric dynamics, Earth system history, climate and climate change, marine and freshwater systems, and ecology. It also considers the interactions between humans and these systems. •Biological sciences Biological sciences encompass all the divisions of natural sciences examining various aspects of vital processes. The concept includes anatomy, physiology, cell biology, biochemistry and biophysics, and covers all organisms from microorganisms, animals to plants. •Health sciences The health sciences study health, disease and healthcare. This field of study aims to develop knowledge, interventions and technology for use in healthcare to improve the treatment of patients.
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