On-chip near-infrared multi-gas sensing using chalcogenide anti-resonant hollow-core waveguides

IF 5.4 2区 工程技术 Q1 BIOCHEMICAL RESEARCH METHODS Lab on a Chip Pub Date : 2025-02-26 DOI:10.1039/D4LC00971A
Yuting Min, Mingquan Pi, Zihang Peng, Gangyun Guan, Lei Liang, Fang Song, Yiding Wang, Yu Zhang, Xue Bai and Chuantao Zheng
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Abstract

On-chip infrared spectroscopic gas sensing using a hollow-core anti-resonant reflecting optical waveguide (ARROW) with a large external confinement factor (ECF) was rarely reported due to the complex fabrication process and polarization dependence. Alternatively, we proposed ARROW gas sensors using chalcogenide (ChG) anti-resonant layers which require thermal evaporation and epoxy resin bonding for fabrication instead of the complicated wafer bonding process. Polarization characteristics and ethylene (C2H2) sensing performance at 1.532 μm were measured for two ARROW sensors with four-side (WG_A) and three-side (WG_B) anti-resonant layers around the hollow-core. Due to a symmetric structure, the 1 cm-long WG_A sensor exhibits polarization-insensitive characteristics, which does not require an additional polarization controller for integrated on-chip sensors and enhances the stability and reliability of the sensor under fluctuating polarization states. A high ECF of 71% and a 1σ limit of detection (LoD) of ∼23 parts-per-million (ppm) for WG_A were achieved at an averaging time of 39.2 s. The broadband multi-gas detection capability of WG_A was verified through C2H2 detection at 1.532 μm and CH4 at 1.654 μm, highlighting the potential of ARROWs for on-chip multi-gas sensing.

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采用硫族抗谐振空心波导的片上近红外多气体传感。
利用大外约束因子(ECF)的空心抗谐振反射光波导(ARROW)进行片上红外光谱气体传感,由于其制作工艺复杂且与偏振相关,报道较少。另外,我们提出了使用硫族化物(ChG)抗谐振层的ARROW气体传感器,该传感器需要热蒸发和环氧树脂粘合来制造,而不是复杂的晶圆粘合过程。采用四边反谐振层(WG_A)和三边反谐振层(WG_B)的ARROW传感器,测量了其在1.532 μm处的极化特性和乙烯(C2H2)传感性能。1 cm长的WG_A传感器由于采用对称结构,具有极化不敏感特性,使得集成片上传感器不需要额外的极化控制器,提高了传感器在波动极化状态下的稳定性和可靠性。在平均39.2 s的时间内,WG_A的ECF高达71%,检测限(LoD)为1σ ~ 23 ppm。通过检测波长为1.532 μm的C2H2和波长为1.654 μm的CH4,验证了WG_A的宽带多气体检测能力,凸显了arrow在片上多气体传感领域的潜力。
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来源期刊
Lab on a Chip
Lab on a Chip 工程技术-化学综合
CiteScore
11.10
自引率
8.20%
发文量
434
审稿时长
2.6 months
期刊介绍: Lab on a Chip is the premiere journal that publishes cutting-edge research in the field of miniaturization. By their very nature, microfluidic/nanofluidic/miniaturized systems are at the intersection of disciplines, spanning fundamental research to high-end application, which is reflected by the broad readership of the journal. Lab on a Chip publishes two types of papers on original research: full-length research papers and communications. Papers should demonstrate innovations, which can come from technical advancements or applications addressing pressing needs in globally important areas. The journal also publishes Comments, Reviews, and Perspectives.
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