Chain length of fatty acid determines the reassembly behaviors of starch-lipid complexes following microwave heat-moisture treatment

IF 9.8 1区 农林科学 Q1 CHEMISTRY, APPLIED Food Chemistry Pub Date : 2025-06-30 Epub Date: 2025-03-05 DOI:10.1016/j.foodchem.2025.143724
Xiaoyan Tan , Fubin Wu , Chengdeng Chi , Zebin Guo , Ying Chen , Bo Chi , Chao Song , Xueshan Xia , Yue Feng , Zhendan He
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Abstract

Food postprocessing can induce the structural changes of starch-lipid complexes, however, how the chain length of fatty acids affects their reassembly behaviors during postprocessing has not been researched. Accordingly, starch-lipid complexes containing varying chain lengths of fatty acids were prepared and the changes in their structures and digestibility were investigated during microwave heat-moisture treatment. After treatment, the contents of complexed lipids, complex index, and single helix in the complexes increased, and the values were lower for complexes containing longer-chain fatty acids. Although more single helices formed for short-chain fatty acids (10 ≤ C ≤ 12), the short-range molecular order and relative crystallinity of the complexes decreased. However, the complexes containing long-chain fatty acids (14 ≤ C ≤ 18) showed the opposite changes. The relative crystallinity of treated samples increased (from 12.0 % to 20.1 %) with increasing chain length of the fatty acids. Moreover, the treated samples exhibited greater enzyme resistance.
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脂肪酸的链长决定了微波热湿处理后淀粉-脂复合物的重组行为
食品后处理可诱导淀粉-脂复合物的结构变化,但脂肪酸链长度如何影响后处理过程中淀粉-脂复合物的重组行为尚未得到研究。为此,制备了含有不同脂肪酸链长的淀粉-脂复合物,并研究了微波热湿处理过程中淀粉-脂复合物结构和消化率的变化。经处理后,配合物中复合脂质的含量、复合指数和单螺旋的含量均有所增加,含长链脂肪酸的配合物的数值较低。虽然短链脂肪酸形成更多的单螺旋(10 ≤ C ≤ 12),但配合物的近程分子有序度和相对结晶度下降。而含有长链脂肪酸的配合物(14 ≤ C ≤ 18)则表现出相反的变化。随着脂肪酸链长的增加,处理后样品的相对结晶度从12.0 %增加到20.1 %。此外,处理后的样品表现出更大的酶抗性。
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麦克林
Stearic acid
麦克林
Palmitic acid
麦克林
Myristic acid
麦克林
Lauric acid
麦克林
Decylic acid
麦克林
Stearic acid
麦克林
Palmitic acid
麦克林
Myristic acid
麦克林
Lauric acid
麦克林
Decylic acid
来源期刊
Food Chemistry
Food Chemistry 工程技术-食品科技
CiteScore
16.30
自引率
10.20%
发文量
3130
审稿时长
122 days
期刊介绍: Food Chemistry publishes original research papers dealing with the advancement of the chemistry and biochemistry of foods or the analytical methods/ approach used. All papers should focus on the novelty of the research carried out.
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