Copper particles-dispersed on graphene oxide has high faradaic efficiency to produce oxalic acid in aprotic medium.

IF 4.9 2区 化学 Q2 CHEMISTRY, PHYSICAL Molecular Catalysis Pub Date : 2025-03-05 DOI:10.1016/j.mcat.2025.114956
Bruna Soares dos Reis Aranha , Fabiana Pereira de Sousa , Alem-Mar Bernardes Goncalves , Gilberto Maia , Diego Carvalho Barbosa Alves
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Abstract

Highlighted by the agreement and meetings promoted by the UN in recent years, it is noted the worldwide concern to combat the emission of greenhouse gases in order to slow the warming of the planet. We report the electrochemical reduction of CO2 to oxalic acid with 48.5 % Faradaic efficiency at -1.0 V (vs. NHE) in aprotic medium. The study shows the influence of copper dispersion on reduced graphene oxide surface as a nanostructured catalyst to produce oxalic acid.

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分散在氧化石墨烯上的铜颗粒在非质子介质中制备草酸具有很高的法拉第效率。
近年来,联合国推动的协议和会议凸显了全球对遏制温室气体排放以减缓地球变暖的关注。我们报道了在非质子介质中,在-1.0 V(相对于NHE)下,以48.5%的法拉第效率将CO2电化学还原为草酸。研究了铜分散体在还原氧化石墨烯表面作为纳米结构催化剂生成草酸的影响。
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来源期刊
Molecular Catalysis
Molecular Catalysis Chemical Engineering-Process Chemistry and Technology
CiteScore
6.90
自引率
10.90%
发文量
700
审稿时长
40 days
期刊介绍: Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are: Heterogeneous catalysis including immobilized molecular catalysts Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis Photo- and electrochemistry Theoretical aspects of catalysis analyzed by computational methods
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