V. V. Avdeeva, A. V. Vologzhanina, V. V. Novikov, G. A. Buzanov, E. A. Malinina, N. T. Kuznetsov
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引用次数: 0
Abstract
The reaction between [Au(Ph3P)Cl] and [B20H18]2– in DMF gave unprecedented heptanuclear cationic gold cluster [Au7(Ph3P)7@C]2+ isolated as [Au7(Ph3P)7@C][B20H18][Au(Ph3P)Cl]·0.5DMF in one step. The final compound was studied by 11B NMR and IR spectroscopies, ESI MS, single-crystal and powder X-ray diffractions. No special reagents were used to obtain central carbon atom in the cluster [Au7(Ph3P)7@C]2+.
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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