E. V. Savinkina, A. E. Gerusova, M. N. Davydova, M. S. Grigoriev, G. A. Buzanov
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引用次数: 0
Abstract
Reaction of zinc halides with methylurea (MeUr) in 1 : 2 ratio in aqueous solution results in formation of new coordination compounds [Zn(MeUr)2Cl2], [Zn(MeUr)2Br2], and [Zn(MeUr)2I2]. The new coordination compounds have been isolated and studied by X-ray powder diffraction, IR spectroscopy, and single-crystal X-ray diffraction. The structure of previously unknown polymorphic modification of zinc bromide complex with dimethylacetamide (DMA) [Zn(DMA)2Br2] has been studied. The complexes have molecular tetrahedral structure. The dipole moments of the zinc halide complexes with methylurea and dimethylacetamide have been calculated to be of 9.3–9.7 D and 6.6–8.2 D, respectively.
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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