Rheological Properties of Polyphenylene Sulfone-Based Compositions as a Basis for Powder Injection Molding and 3D Printing Technology

IF 1.1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series A Pub Date : 2025-01-31 DOI:10.1134/S0965545X24601230
A. L. Slonov, A. A. Zhansitov, I. V. Musov, A. A. Khashirov, A. V. Mityukov, A. Ya. Malkin, S. Yu. Khashirova
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Abstract

The rheological properties of suspensions based on paraffin and LDPE, in which polyphenylene sulfone powder is dispersed, intended for powder injection molding and 3D printing were studied. Compositions with a polymer content of up to 50 vol % are pseudoplastic liquids that lose their flow ability upon reaching 60 vol %. Suspensions with 30 and 40 vol % polyphenylene sulfone have optimal technological properties during injection molding, combining the required rheological properties and strength of products. At the same time, compositions with PE have sufficient fluidity only at 180°C, while elastic deformations dominate at lower temperatures. The best quality of 3D printing is achieved using a composition based on a matrix of paraffin and PE (30 : 70), with a polyphenylene sulfone content of 40 vol %.

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作为粉末注射成型和 3D 打印技术基础的聚苯砜基复合材料的流变特性
研究了分散聚苯砜粉末的石蜡和LDPE悬浮液在粉末注射成型和3D打印中的流变性能。聚合物含量高达50 vol %的组合物是假塑性液体,在达到60 vol %时失去其流动能力。含有30和40 vol %聚苯砜的悬浮液在注塑成型过程中具有最佳的技术性能,结合了所需的流变性能和产品的强度。同时,含PE的组合物只有在180℃时才有足够的流动性,而在较低温度下,弹性变形占主导地位。使用基于石蜡和PE(30:70)基质的组合物,聚苯砜含量为40 vol %,可以实现最佳质量的3D打印。
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来源期刊
Polymer Science, Series A
Polymer Science, Series A 化学-高分子科学
CiteScore
1.70
自引率
0.00%
发文量
55
审稿时长
3 months
期刊介绍: Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.
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