Synthesis, Crystal Structure and Spectral Characterization of 5-Methyl-2-(Propan-2-yl)Cyclohexyl Cyanoacetate and 1,3,3-Trimethylbicyclo[2.2.1]Heptan-2-yl Cyanoacetate
F. S. Mohamed, J. Bąkowicz, B. Dziuk, G. A. M. Nawwar
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引用次数: 0
Abstract
The titled compounds are synthesized using a conventional esterification method, involving the reaction of the desired alcohol with cyanoacetic acid. Single crystal is obtained through recrystallization. The compounds are characterized using elemental analysis, IR, 1H NMR, 13C NMR spectroscopy, and mass spectrometry. The structural parameters, including bond distances and angles, are analyzed and discussed based on X-ray study result. The study reveals that the hydrogen atoms of the methylene groups in the two synthesized compounds exhibit a rigid C–H rotating group. The absolute configuration of the stereogenic centers in both compounds is consistent with the substrate used in their synthesis.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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