Multiple proxies to investigate the submarine groundwater discharge into the Arabian Sea, Southwest coast, India: integration of biogeochemical, geophysical, and remote sensing techniques

Abstract

Submarine Groundwater Discharge (SGD) constitutes a pivotal mechanism for the transference of freshwater, nutrients, and pollutants from terrestrial to marine environments, exerting a profound influence on coastal water quality and ecosystem dynamics. In this investigation, we executed an extensive field sampling campaign along the 650 km coastal expanse of southwest India, employing a 10-km sampling interval, to discern and validate the probable zones of SGD. We have utilized a transect-based methodology for the systematic collection of groundwater, porewater, and seawater samples, employing a suite of proxies to scrutinize SGD). This multifaceted approach encompassed biogeochemical, geophysical, and remote sensing techniques. The in situ physio-chemical parameters, encompassing electrical conductivity (EC), total dissolved solids (TDS), pH, dissolved oxygen (DO), temperature, and salinity, facilitated the delineation of prospective SGD sites. Adjacent continuous probable SGD sites were amalgamated into nine potential SGD zones spanning the 650 km coastal stretch. Comprehensive analyses of major ions and nutrients revealed maximum observed seawater concentrations of nitrate, phosphate, and silica at 22.11 µM/L, 12.5 µM/L, and 11.69 µM/L, respectively, underscoring the SGD signatures and the subsequent transference of nutrients from terrestrial sources to the ocean via subsurface pathways. Furthermore, geophysical investigations employing Electrical Resistivity Tomography (ERT) at the nine potential SGD zones substantiated the groundwater signatures, elucidating subsurface lithology, delineating the aquifer system, and determining the extent of the saline-freshwater interface, including discharge depth. All ERT profiles were meticulously calibrated against available lithological data. Additionally, we executed a comprehensive evaluation of Landsat-8 satellite imagery within the thermal infrared spectral domain (10.6–11.19 μm) to monitor variations in sea surface temperature (SST) and sea surface anomalies across three stratified thermal ranges (21–28 °C, 25–33 °C, and 11–23 °C) encompassing the entire study area. The visual correlation observed between lower SST values and the identified SGD probable zones further substantiates supplementary validation. Ultimately, the verification of these nine prospective SGD zones was reinforced through a meticulous comparison with groundwater level data, which ranged from 0 to 41 m above mean sea level (MSL). This extensive investigation represents the inaugural comprehensive identification and confirmation of SGD zones along the southwest coast of India, spanning a 650-km stretch, resulting in a more precise demarcation of the area into nine SGD probable zones where multiple proxies are mutually corroborative.