Research on the performance of coagulation with dual high molecular weight flocculant PAC-NPAM for the treatment of Cr (VI) containing wastewater in a magnetic levitation fixed bed

IF 4.3 2区 工程技术 Q2 ENGINEERING, CHEMICAL Chemical Engineering Science Pub Date : 2025-03-11 DOI:10.1016/j.ces.2025.121518
Yunxiao Ban, Zhijie Wan, Cong Ma, Yuzhen Wu, Haoran Chen
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Abstract

This study proposes a magnetic levitation fixed bed flocculation reactor as an effective method for the removal of Cr (VI). The research examines the effects of both single and dual polymer flocculants on the efficiency of the flocculation process. Initially, a magnetic levitation layer was established using a radial magnetic field in conjunction with stainless steel balls. Subsequently, polyaluminum chloride (PAC) and a non-ionic coagulant, polyacrylamide (NPAM), were introduced into the water to create a magnetic levitation fixed bed flocculation reactor. This reactor with the objective of purifying water contaminated with simulated Cr (VI).
The results indicate that the incorporation of a reducing agent, specifically FeSO4, in conjunction with PAC and NPAM respectively, can achieve Cr (VI) removal rates exceeding 97% and turbidity removal rates exceeding 96%. The interaction between the cross-flow influent and the flocculating particles promotes the formation of micro-vortex flocculation.
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双高分子量絮凝剂PAC-NPAM在磁悬浮固定床中处理含铬废水的混凝性能研究
本研究提出了磁悬浮固定床絮凝反应器作为去除Cr (VI)的有效方法。研究考察了单、双高分子絮凝剂对絮凝过程效率的影响。最初,利用径向磁场和不锈钢球建立了一个磁悬浮层。随后,将聚合氯化铝(PAC)和非离子混凝剂聚丙烯酰胺(NPAM)引入水中,形成磁悬浮固定床絮凝反应器。该反应器以净化模拟Cr (VI)污染的水为目的。结果表明,还原剂,特别是FeSO4,分别与PAC和NPAM联合使用,Cr (VI)去除率超过97%,浊度去除率超过96%。横流进水与絮凝颗粒的相互作用促进了微涡絮凝的形成。
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阿拉丁
diphenylcarbazone
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ferrous sulfate
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hydrochloric acid
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potassium dichromate
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sodium hydroxide
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kaolin
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poly aluminum chloride
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polyacrylamide
来源期刊
Chemical Engineering Science
Chemical Engineering Science 工程技术-工程:化工
CiteScore
7.50
自引率
8.50%
发文量
1025
审稿时长
50 days
期刊介绍: Chemical engineering enables the transformation of natural resources and energy into useful products for society. It draws on and applies natural sciences, mathematics and economics, and has developed fundamental engineering science that underpins the discipline. Chemical Engineering Science (CES) has been publishing papers on the fundamentals of chemical engineering since 1951. CES is the platform where the most significant advances in the discipline have ever since been published. Chemical Engineering Science has accompanied and sustained chemical engineering through its development into the vibrant and broad scientific discipline it is today.
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