Yuan-Gen Lu, Bo Hao, Geng Chen, Cai-Xian Xu, Li Zhang
{"title":"Analysis of Burning Rate Variation of Tungsten Delay Composition Close to Zero Oxygen Balance","authors":"Yuan-Gen Lu, Bo Hao, Geng Chen, Cai-Xian Xu, Li Zhang","doi":"10.1002/fam.3279","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>Tungsten delay compositions are widely utilized in ammunition, small detonators, and other devices. In this study, we first explored the changes in the burning rate of micron-sized tungsten delay compositions (W/BaCrO<sub>4</sub>/KClO<sub>4</sub>) when achieving zero oxygen balance under different material tube walls. Subsequently, SiO<sub>2</sub>, CuO, BN, and shellac were added to the tungsten delay composition to investigate the burning rate variations of different samples in aluminum tubes. The experimental results reveal that the combustion rate of the tungsten delay composition decreases with an increase in the thermal conductivity of the tube wall. The content of BN exhibits a linear relationship with the combustion rate of the tungsten delay composition, the combustion rate of the tungsten delay composition decreases with the increase of the mass percentage of BN. A small amount of SiO<sub>2</sub>, CuO, and shellac accelerates the combustion rate of the tungsten delay composition, but the combustion rate decreases as the content of these additives increases. The conclusion of this study can provide a wider range of delay times for delay devices with significant spatial limitations.</p>\n </div>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 3","pages":"320-328"},"PeriodicalIF":2.0000,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fire and Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/fam.3279","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Tungsten delay compositions are widely utilized in ammunition, small detonators, and other devices. In this study, we first explored the changes in the burning rate of micron-sized tungsten delay compositions (W/BaCrO4/KClO4) when achieving zero oxygen balance under different material tube walls. Subsequently, SiO2, CuO, BN, and shellac were added to the tungsten delay composition to investigate the burning rate variations of different samples in aluminum tubes. The experimental results reveal that the combustion rate of the tungsten delay composition decreases with an increase in the thermal conductivity of the tube wall. The content of BN exhibits a linear relationship with the combustion rate of the tungsten delay composition, the combustion rate of the tungsten delay composition decreases with the increase of the mass percentage of BN. A small amount of SiO2, CuO, and shellac accelerates the combustion rate of the tungsten delay composition, but the combustion rate decreases as the content of these additives increases. The conclusion of this study can provide a wider range of delay times for delay devices with significant spatial limitations.
期刊介绍:
Fire and Materials is an international journal for scientific and technological communications directed at the fire properties of materials and the products into which they are made. This covers all aspects of the polymer field and the end uses where polymers find application; the important developments in the fields of natural products - wood and cellulosics; non-polymeric materials - metals and ceramics; as well as the chemistry and industrial applications of fire retardant chemicals.
Contributions will be particularly welcomed on heat release; properties of combustion products - smoke opacity, toxicity and corrosivity; modelling and testing.