Systemically study of microstructure, mechanical and corrosion properties in biodegradable Zn-0.5Mn-0.2Mg alloys by rolling and heat treatment

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Journal of Alloys and Compounds Pub Date : 2025-03-16 DOI:10.1016/j.jallcom.2025.179774
Hailing Chen , Xiang Lu , Lebin Tang , Tao Sun , Quanxin Chen , Xinglong Zhu , Shengci Li , Qingke Zhang , Lijing Yang , Zhenlun Song
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Abstract

In this study, Zn-0.5Mn-0.2Mg alloys were prepared by hot-rolled and heat-treated at 100–300 °C. The microstructure, mechanical and corrosion properties were systemically investigated. It was found that the MnZn13, Mg2Zn11 second phases and texture are similar for the rolled and heat-treatment sample, but the grain size increased from 1.64 μm to 11.24 μm with the increasing heat-treatment temperature. The tensile strength increased and ductility decreased after heat treatment, and the maximum strength of 305 MPa was obtained at 300 °C. The improved strength was mainly attributed to the increased grain size which reduced the dominant grain boundary slip. Another result is that the localized corrosion phenomenon is reduced after heat treatment, especially for 200 °C heat-treated sample. In addition, the heat treatment has not deteriorated the cell viability of L-929 and shows no-toxicity in 25 % extract. The study demonstrates that heat treatment after rolling is a promising approach to improve the comprehensive properties of biodegradable Zn alloys.
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系统研究了生物降解Zn-0.5Mn-0.2Mg合金轧制和热处理后的显微组织、力学性能和腐蚀性能
本研究采用热轧法制备Zn-0.5Mn-0.2Mg合金,并在100-300℃下进行热处理。系统地研究了其显微组织、力学性能和腐蚀性能。结果表明,轧制后和热处理后的MnZn13、Mg2Zn11第二相组织基本一致,但随着热处理温度的升高,MnZn13、Mg2Zn11第二相的晶粒尺寸从1.64 μm增大到11.24 μm。热处理后拉伸强度提高,塑性降低,在300℃时达到最大强度305 MPa。强度的提高主要是由于晶粒尺寸的增大减少了主导晶界滑移。另一个结果是热处理后的局部腐蚀现象减少,特别是对200℃热处理样品。另外,25%提取物的热处理对L-929的细胞活力没有影响,对L-929也没有毒性。研究表明,轧制后热处理是提高生物降解锌合金综合性能的有效途径。
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来源期刊
Journal of Alloys and Compounds
Journal of Alloys and Compounds 工程技术-材料科学:综合
CiteScore
11.10
自引率
14.50%
发文量
5146
审稿时长
67 days
期刊介绍: The Journal of Alloys and Compounds is intended to serve as an international medium for the publication of work on solid materials comprising compounds as well as alloys. Its great strength lies in the diversity of discipline which it encompasses, drawing together results from materials science, solid-state chemistry and physics.
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