Synthesis of a New Bis-4-Cumyl Phenoxy Phthalocyaninato Silicon (IV) and Its Evaluation on Selectivity for Iron (III) Ions

IF 3.7 2区化学 Q2 CHEMISTRY, APPLIED Applied Organometallic Chemistry Pub Date : 2025-03-16 DOI:10.1002/aoc.70120

Mehmet Salih Ağırtaş, Derya Güngördü Solğun

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Abstract

Axial phthalocyanine compound carrying 4-cumyl phenoxy groups was obtained from the reaction of 4-cumyl phenol with silicon phthalocyanine dichloride (SiPcCl₂). The compound was characterized by ¹H NMR, UV–visible light, FTIR, and mass spectrum. Electronic properties and photochemical properties of the compound were investigated by UV–visible light spectra. Singlet oxygen production capacity for the compound was investigated, and the singlet oxygen production (Φ∆) value was found to be 0.14. The sensor potential of the compound was investigated by UV–visible light spectra against magnesium (II) ions (Mg²⁺), manganese (II) ions (Mn²⁺), sodium (I) ions (Na⁺), nickel (II) ions (Ni²⁺), zinc (II) ions (Zn²⁺), silver (I) ions (Ag⁺), barium (II) ions (Ba²⁺), cadmium (II) ions (Cd²⁺), copper (II) ions (Cu²⁺), cobalt (II) ions (Co²⁺), and iron (III) ions (Fe³⁺). The selective sensitivity of the phthalocyanine compound only to Fe³⁺ ions enables the practical analysis of Fe³⁺ ions in many environments. This study presents an alternative and practically applicable method for the sensitive determination of Fe³⁺ ions, which have widespread adverse effects on the environment, ecosystem and human health.

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一种新的双-4-异丙基苯氧基酞菁硅 (IV) 的合成及其对铁 (III) 离子选择性的评估

以4-五甲基苯酚与二氯化酞菁硅（SiPcCl2）为原料，合成了含4-五甲基苯氧基的轴向酞菁化合物。通过1H NMR、uv -可见光、FTIR和质谱对化合物进行了表征。利用紫外-可见光谱研究了化合物的电子性质和光化学性质。考察了该化合物的单线态产氧能力，发现单线态产氧（Φ∆）值为0.14。通过紫外可见光谱研究了该化合物对镁（II）离子（Mg2+）、锰（II）离子（Mn2+）、钠(I)离子（Na+）、镍（II）离子（Ni2+）、锌（II）离子（Zn2+）、银(I)离子（Ag+）、钡（II）离子（Ba2+）、镉（II）离子（Cd2+）、铜（II）离子（Cu2+）、钴（II）离子（Co2+）和铁（III）离子（Fe3+）的感应电位。酞菁化合物仅对Fe3+离子的选择性敏感性使得在许多环境中对Fe3+离子的实际分析成为可能。本研究提出了一种可替代的、实际适用的方法来灵敏测定对环境、生态系统和人类健康有广泛不利影响的Fe3+离子。

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来源期刊

Applied Organometallic Chemistry 化学-无机化学与核化学

CiteScore

7.80

自引率

10.30%

发文量

408

审稿时长

2.2 months

期刊介绍： All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.