Surface modification of polyether ether ketone (PEEK) via sulfonation and hydroxyapatite coating: impact on shear bond strength with resin composite.

IF 3.1 2区医学 Q1 DENTISTRY, ORAL SURGERY & MEDICINE Clinical Oral Investigations Pub Date : 2025-03-15 DOI:10.1007/s00784-025-06256-x

Thae Phyu Htay, Chaimongkon Peampring, Putsadeeporn Thammajaruk

{"title":"Surface modification of polyether ether ketone (PEEK) via sulfonation and hydroxyapatite coating: impact on shear bond strength with resin composite.","authors":"Thae Phyu Htay, Chaimongkon Peampring, Putsadeeporn Thammajaruk","doi":"10.1007/s00784-025-06256-x","DOIUrl":null,"url":null,"abstract":"Purpose: This study evaluates the effects of various polyetheretherketone (PEEK) surface treatments on its shear bond strength (SBS) with flowable resin composite.Methods: A total of 120 PEEK disks were categorized into five groups: untreated PEEK (control), sandblasted with 50 μm alumina (Sa PEEK), etched with 98% sulfuric acid for 1 min (S PEEK), hydroxyapatite-coated sulfonated PEEK (HA PEEK), and phosphoric acid-etched HA-coated PEEK (HAP PEEK). Each group was subdivided into two groups (n = 12): Scotchbond Universal Plus (Scb) and Single Bond Universal (Sib) adhesive application and bond with flowable resin composite. SBS was evaluated after thermocycling for 5000 cycles and the results were analyzed using two-way and one-way ANOVA, followed by Tukey's HSD (α = 0.05). Failure mode was analyzed using light and scanning electron microscope. Surface roughness and contact angle analysis of each surface treatment were also done.Results: HA PEEK exhibited the highest SBS in both Scb and Sib, while untreated PEEK showed the lowest. The effect of bonding agent can be seen only in S PEEK group where Sib demonstrated significantly higher SBS (P < 0.05) than Scb. Cohesive and mixed failures were observed in HA PEEK and HAP PEEK groups and others showed mostly adhesive failure. The wettability of PEEK increased after surface treatment except for Sa PEEK.Conclusions: HA PEEK consistently achieved the highest SBS, indicating that combining sulfonation with HA coating is an effective strategy to enhance bonding between PEEK and flowable resin composite.","PeriodicalId":10461,"journal":{"name":"Clinical Oral Investigations","volume":"29 4","pages":"184"},"PeriodicalIF":3.1000,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Clinical Oral Investigations","FirstCategoryId":"3","ListUrlMain":"https://doi.org/10.1007/s00784-025-06256-x","RegionNum":2,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"DENTISTRY, ORAL SURGERY & MEDICINE","Score":null,"Total":0}

引用次数: 0

Abstract

Purpose: This study evaluates the effects of various polyetheretherketone (PEEK) surface treatments on its shear bond strength (SBS) with flowable resin composite.

Methods: A total of 120 PEEK disks were categorized into five groups: untreated PEEK (control), sandblasted with 50 μm alumina (Sa PEEK), etched with 98% sulfuric acid for 1 min (S PEEK), hydroxyapatite-coated sulfonated PEEK (HA PEEK), and phosphoric acid-etched HA-coated PEEK (HAP PEEK). Each group was subdivided into two groups (n = 12): Scotchbond Universal Plus (Scb) and Single Bond Universal (Sib) adhesive application and bond with flowable resin composite. SBS was evaluated after thermocycling for 5000 cycles and the results were analyzed using two-way and one-way ANOVA, followed by Tukey's HSD (α = 0.05). Failure mode was analyzed using light and scanning electron microscope. Surface roughness and contact angle analysis of each surface treatment were also done.

Results: HA PEEK exhibited the highest SBS in both Scb and Sib, while untreated PEEK showed the lowest. The effect of bonding agent can be seen only in S PEEK group where Sib demonstrated significantly higher SBS (P < 0.05) than Scb. Cohesive and mixed failures were observed in HA PEEK and HAP PEEK groups and others showed mostly adhesive failure. The wettability of PEEK increased after surface treatment except for Sa PEEK.

Conclusions: HA PEEK consistently achieved the highest SBS, indicating that combining sulfonation with HA coating is an effective strategy to enhance bonding between PEEK and flowable resin composite.

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

Clinical Oral Investigations 医学-牙科与口腔外科

CiteScore

6.30

自引率

5.90%

发文量

484

审稿时长

3 months

期刊介绍： The journal Clinical Oral Investigations is a multidisciplinary, international forum for publication of research from all fields of oral medicine. The journal publishes original scientific articles and invited reviews which provide up-to-date results of basic and clinical studies in oral and maxillofacial science and medicine. The aim is to clarify the relevance of new results to modern practice, for an international readership. Coverage includes maxillofacial and oral surgery, prosthetics and restorative dentistry, operative dentistry, endodontics, periodontology, orthodontics, dental materials science, clinical trials, epidemiology, pedodontics, oral implant, preventive dentistiry, oral pathology, oral basic sciences and more.