Revisiting polymer coatings on nanoparticles: correlation between molecular weight and coating thickness in chain transfer polymerizations†

IF 3.9 2区 化学 Q2 POLYMER SCIENCE Polymer Chemistry Pub Date : 2025-03-18 DOI:10.1039/D5PY00081E
Daniel Döpping, Andreas Stihl, Dominik Voll, Felix H. Schacher and Patrick Théato
{"title":"Revisiting polymer coatings on nanoparticles: correlation between molecular weight and coating thickness in chain transfer polymerizations†","authors":"Daniel Döpping, Andreas Stihl, Dominik Voll, Felix H. Schacher and Patrick Théato","doi":"10.1039/D5PY00081E","DOIUrl":null,"url":null,"abstract":"<p >Various poly(methyl methacrylate) (PMMA) and poly(acrylonitrile) (PAN) coated silica nanoparticles were synthesized <em>via</em> chain transfer polymerization with the goal to assess the coating behavior and characterization of polymer coated silica nanoparticles with monomers of different reactivities. The particles were characterized by TGA, EDXS, TEM and correlated to the free PMMA/PAN formed in the crude reaction mixture characterized with SEC. It was found that the mass loss observed in TGA and coating thickness obtained from TEM micrographs correlate strongly with the average polymer chain-length in the crude reaction mixture.</p>","PeriodicalId":100,"journal":{"name":"Polymer Chemistry","volume":" 18","pages":" 2075-2082"},"PeriodicalIF":3.9000,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/py/d5py00081e?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/py/d5py00081e","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

Abstract

Various poly(methyl methacrylate) (PMMA) and poly(acrylonitrile) (PAN) coated silica nanoparticles were synthesized via chain transfer polymerization with the goal to assess the coating behavior and characterization of polymer coated silica nanoparticles with monomers of different reactivities. The particles were characterized by TGA, EDXS, TEM and correlated to the free PMMA/PAN formed in the crude reaction mixture characterized with SEC. It was found that the mass loss observed in TGA and coating thickness obtained from TEM micrographs correlate strongly with the average polymer chain-length in the crude reaction mixture.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
纳米颗粒聚合物涂层:链转移聚合中分子量和涂层厚度的关系
采用链转移聚合法制备了不同反应活性单体的聚甲基丙烯酸甲酯(PMMA)和聚丙烯腈(PAN)包覆二氧化硅纳米颗粒,研究了不同反应活性单体包覆二氧化硅纳米颗粒的性能。通过热重分析(TGA)、能量色散x射线光谱(EDXS)、透射电镜(TEM)对颗粒进行了表征,并与粗反应混合物中形成的游离PMMA/PAN进行了相关性分析,并用粒径排除色谱(SEC)对其进行了表征。结果表明,热重分析仪测得的质量损失和透射电镜测得的涂层厚度与粗反应混合物中聚合物的平均链长密切相关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Polymer Chemistry
Polymer Chemistry POLYMER SCIENCE-
CiteScore
8.60
自引率
8.70%
发文量
535
审稿时长
1.7 months
期刊介绍: Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
期刊最新文献
Elucidating the Molecular Design Principles of N-Alkylated Nylons for LCST-Type Phase Separation through a Systematic Polymer Library Synthesis of Optically Active Polymers Containing a Main-Chain Hydroxamic Acid Backbone via Asymmetric Polymerization Palladium-catalyzed copolymerization to synthesize sulfur-containing polyethylene materials Inner Side-Chain Engineering of Non-Fullerene Acceptors Enables Efficient Thick-Film All-Polymer Solar Cells Modulatable Structural Colors in Rapid-Curing High-Performance Hydrogels
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1