Doping Engineering Strategy for Boosting the Performance of AlGaN-Based Deep-Ultraviolet Light-Emitting Diodes

IF 3.4 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Crystal Growth & Design Pub Date : 2025-02-27 DOI:10.1021/acs.cgd.4c01612
Xu Liu, Jiahao Song, Zhenxing Lv, Zhefu Liao, Hansong Geng, Ziqi Zhang, Jingjing Jiang, Bin Tang, Shengli Qi, Sheng Liu and Shengjun Zhou*, 
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Abstract

AlGaN-based light-emitting diodes (LEDs) operating in the deep-ultraviolet (DUV) spectral range have exhibited a promising future in physical sterilization. However, the low Mg doping efficiency hinders the further development of high-performance AlGaN-based DUV LEDs. Herein, we demonstrate the performance of 279 nm AlGaN-based DUV LEDs beyond the state-of-the-art by exploiting the periodic Mg doping strategy. In contrast to continuous doping, periodic doping can improve the crystalline quality and the Mg distribution in the p-Al0.66Ga0.34N layer, thereby achieving higher doping efficiency of Mg dopants with lower doping concentration. As a result, after forming the periodic-doping electron-blocking layer (EBL), the light output power (LOP) of the DUV LED is improved by 92.4% at 300 mA in contrast to its referred counterpart with continuous-doping EBL. Our work is able to provide a new horizon in the development of highly efficient AlGaN-based DUV emitters.

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提高algan基深紫外发光二极管性能的掺杂工程策略
在深紫外光谱范围内工作的海藻基发光二极管(led)在物理杀菌方面具有广阔的应用前景。然而,低Mg掺杂效率阻碍了高性能algan基DUV led的进一步发展。在此,我们通过利用周期性Mg掺杂策略,证明了279 nm algan基DUV led的性能超越了最先进的水平。与连续掺杂相比,周期性掺杂可以改善p-Al0.66Ga0.34N层的晶体质量和Mg的分布,从而在较低掺杂浓度下获得较高的Mg掺杂效率。结果表明,在形成周期性掺杂电子阻挡层(EBL)后,与连续掺杂电子阻挡层相比,DUV LED在300 mA时的光输出功率(LOP)提高了92.4%。我们的工作能够为开发高效的海藻基DUV发射器提供新的视野。
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来源期刊
Crystal Growth & Design
Crystal Growth & Design 化学-材料科学:综合
CiteScore
6.30
自引率
10.50%
发文量
650
审稿时长
1.9 months
期刊介绍: The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials. Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.
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