Jun-Rui Liu , Yao-Mei Fu , Yu-Ou He , Wen-Tao Ju , Xing Meng , Hai-Ning Wang , Zhong-Min Su
{"title":"A MOF-on-MOF composite enhances visible light photocatalytic CO2 reduction performance","authors":"Jun-Rui Liu , Yao-Mei Fu , Yu-Ou He , Wen-Tao Ju , Xing Meng , Hai-Ning Wang , Zhong-Min Su","doi":"10.1016/j.jssc.2025.125323","DOIUrl":null,"url":null,"abstract":"<div><div>Photocatalytic CO<sub>2</sub> reduction (Pc-CO<sub>2</sub>RR) offers one way to covert CO<sub>2</sub> into useful chemicals. MOF-on-MOF materials can be made for Pc-CO<sub>2</sub>RR with instinct performance. This work provides a family of MOF-on-MOF photocatalysts, <strong>IEF-11@Zr-TCPP</strong> for Pc-CO<sub>2</sub>RR via the gas-solid mode. Owing to the appropriate synergistic effect between two MOF components, <strong>IEF-11@Zr-TCPP</strong> displayed high CO evolution rates of 201.71 (in pure CO<sub>2</sub>) or 245.34 μmol g<sup>−1</sup> h<sup>−1</sup> (in diluted CO<sub>2</sub>) respectively, without auxiliary photosensitizers or sacrificial agents. This study helps to discover new MOF based photocatalytic systems that collect solar energy and exhibit high catalytic activity with no cocatalyst.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125323"},"PeriodicalIF":3.2000,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Solid State Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S002245962500146X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Photocatalytic CO2 reduction (Pc-CO2RR) offers one way to covert CO2 into useful chemicals. MOF-on-MOF materials can be made for Pc-CO2RR with instinct performance. This work provides a family of MOF-on-MOF photocatalysts, IEF-11@Zr-TCPP for Pc-CO2RR via the gas-solid mode. Owing to the appropriate synergistic effect between two MOF components, IEF-11@Zr-TCPP displayed high CO evolution rates of 201.71 (in pure CO2) or 245.34 μmol g−1 h−1 (in diluted CO2) respectively, without auxiliary photosensitizers or sacrificial agents. This study helps to discover new MOF based photocatalytic systems that collect solar energy and exhibit high catalytic activity with no cocatalyst.
期刊介绍:
Covering major developments in the field of solid state chemistry and related areas such as ceramics and amorphous materials, the Journal of Solid State Chemistry features studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids.