A MOF-on-MOF composite enhances visible light photocatalytic CO2 reduction performance

IF 3.5 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Journal of Solid State Chemistry Pub Date : 2025-03-15 DOI:10.1016/j.jssc.2025.125323
Jun-Rui Liu , Yao-Mei Fu , Yu-Ou He , Wen-Tao Ju , Xing Meng , Hai-Ning Wang , Zhong-Min Su
{"title":"A MOF-on-MOF composite enhances visible light photocatalytic CO2 reduction performance","authors":"Jun-Rui Liu ,&nbsp;Yao-Mei Fu ,&nbsp;Yu-Ou He ,&nbsp;Wen-Tao Ju ,&nbsp;Xing Meng ,&nbsp;Hai-Ning Wang ,&nbsp;Zhong-Min Su","doi":"10.1016/j.jssc.2025.125323","DOIUrl":null,"url":null,"abstract":"<div><div>Photocatalytic CO<sub>2</sub> reduction (Pc-CO<sub>2</sub>RR) offers one way to covert CO<sub>2</sub> into useful chemicals. MOF-on-MOF materials can be made for Pc-CO<sub>2</sub>RR with instinct performance. This work provides a family of MOF-on-MOF photocatalysts, <strong>IEF-11@Zr-TCPP</strong> for Pc-CO<sub>2</sub>RR via the gas-solid mode. Owing to the appropriate synergistic effect between two MOF components, <strong>IEF-11@Zr-TCPP</strong> displayed high CO evolution rates of 201.71 (in pure CO<sub>2</sub>) or 245.34 μmol g<sup>−1</sup> h<sup>−1</sup> (in diluted CO<sub>2</sub>) respectively, without auxiliary photosensitizers or sacrificial agents. This study helps to discover new MOF based photocatalytic systems that collect solar energy and exhibit high catalytic activity with no cocatalyst.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"347 ","pages":"Article 125323"},"PeriodicalIF":3.5000,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Solid State Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S002245962500146X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Photocatalytic CO2 reduction (Pc-CO2RR) offers one way to covert CO2 into useful chemicals. MOF-on-MOF materials can be made for Pc-CO2RR with instinct performance. This work provides a family of MOF-on-MOF photocatalysts, IEF-11@Zr-TCPP for Pc-CO2RR via the gas-solid mode. Owing to the appropriate synergistic effect between two MOF components, IEF-11@Zr-TCPP displayed high CO evolution rates of 201.71 (in pure CO2) or 245.34 μmol g−1 h−1 (in diluted CO2) respectively, without auxiliary photosensitizers or sacrificial agents. This study helps to discover new MOF based photocatalytic systems that collect solar energy and exhibit high catalytic activity with no cocatalyst.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
MOF-on-MOF复合材料增强了可见光光催化CO2还原性能
光催化CO2还原(Pc-CO2RR)提供了一种将CO2转化为有用化学物质的方法。MOF-on-MOF材料可用于具有本能性能的Pc-CO2RR。这项工作提供了一系列MOF-on-MOF光催化剂,IEF-11@Zr-TCPP通过气固模式用于Pc-CO2RR。在不使用辅助光敏剂和牺牲剂的情况下,IEF-11@Zr-TCPP的CO析出率分别为201.71 μmol g−1 h−1(稀释CO2)和245.34 μmol g−1(纯CO2)。该研究有助于发现新的基于MOF的光催化系统,该系统可以收集太阳能,并且在没有助催化剂的情况下具有高催化活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Journal of Solid State Chemistry
Journal of Solid State Chemistry 化学-无机化学与核化学
CiteScore
6.00
自引率
9.10%
发文量
848
审稿时长
25 days
期刊介绍: Covering major developments in the field of solid state chemistry and related areas such as ceramics and amorphous materials, the Journal of Solid State Chemistry features studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids.
期刊最新文献
Editorial Board Contents continued Interface engineering coupled with NiAl-LDH/Ti3C2Tx sacrificial template: Fabrication of 3D flower-like NiO/Al2O3/TiO2 composites and their DMF gas-sensing performances Magnetism, orbital splitting and electron–phonon coupling of chalcogenide "11" type iron-based superconductors under high pressure Iron and nickel vs. cobalt: Precipitation of tris-chelate phenanthroline complexes [ML3][B12Cl12] from the solution
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1