{"title":"Selective oxidation of aromatic olefins to aldehydes with hydrogen peroxide over V-ZSM-5 catalyst","authors":"Xuewei Xu, Jiaming Guo, Yaya Wang, Shunli Du, Xinyue Zhang, Xinhua Peng","doi":"10.1016/j.tet.2025.134592","DOIUrl":null,"url":null,"abstract":"<div><div>The selective oxidation of aromatic olefins to aromatic aldehydes is efficiently employed by using hydrogen peroxide as clean oxidant in the presence of the catalyst of vanadium supported on ZSM-5. The 56.1 % of conversion for substrate styrene is obtained in 90.8 % of selectivity for product benzaldehyde. The mechanism involving an ethylbenzene peroxide active intermediate is proposed to realize the reaction. In comparison to traditional methods, the newly designed multiphase catalytic system embodies principles of green sustainable development and exhibits enhanced environmental friendliness towards a promising industrial application.</div></div>","PeriodicalId":437,"journal":{"name":"Tetrahedron","volume":"178 ","pages":"Article 134592"},"PeriodicalIF":2.1000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040402025001486","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
The selective oxidation of aromatic olefins to aromatic aldehydes is efficiently employed by using hydrogen peroxide as clean oxidant in the presence of the catalyst of vanadium supported on ZSM-5. The 56.1 % of conversion for substrate styrene is obtained in 90.8 % of selectivity for product benzaldehyde. The mechanism involving an ethylbenzene peroxide active intermediate is proposed to realize the reaction. In comparison to traditional methods, the newly designed multiphase catalytic system embodies principles of green sustainable development and exhibits enhanced environmental friendliness towards a promising industrial application.
期刊介绍：
Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry.
Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters.
Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.
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