Decoupling fracture energy from crack area via surface patterning

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Surfaces and Interfaces Pub Date : 2025-04-01 Epub Date: 2025-03-12 DOI:10.1016/j.surfin.2025.106066
Ping Hu , Shuangshung Li , Michal K. Budzik
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Abstract

This study investigates whether surface patterning can decouple fracture energy from treated area fractions and examines the relationship between surface wettability and fracture energy. By using a nanosecond pulsed laser to create square-shaped patterns on AA7075-T6 aluminum surfaces, we explore the impact of pattern size on wettability and fracture behavior, offering new insights into optimizing surface treatments for enhanced material performance. The pattern sizes ranged from the micrometer to millimeter scale, with reference samples, including fully untreated and fully laser-treated surfaces, also prepared and tested.
Wettability assessments revealed that increasing the laser-treated area fraction significantly enhanced wetting. Distinct differences between micro- and larger patterns were observed, with larger patterns altering the wetting area’s shape and reducing the effective contact angle. These findings highlighted a direct link between pattern geometry and wettability, which is important for predicting and controlling fracture energy.
Laser treatment profoundly impacted fracture energy and failure modes of epoxy bonded aluminum adherends. Untreated samples exhibited adhesive failure at low fracture energy values, whereas fully treated samples showed cohesive failure with fracture energy nine times higher. Intermediate cases displayed a mix of the two failure modes. Theoretical and numerical models were developed to predict and interpret these experimental results, highlighting that surface pattern size significantly influences adhesion and fracture properties.
The results suggest that fracture energy cannot be uniquely predicted by the treated area fraction alone, underscoring the potential of precise surface patterning to control crack growth resistance and suggesting a relationship between wettability and fracture energy.

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通过表面图案从裂纹区域解耦断裂能
本研究探讨了表面图案是否可以将压裂能从处理区域的馏分中分离出来,并研究了表面润湿性与压裂能之间的关系。通过使用纳秒脉冲激光在AA7075-T6铝表面创建方形图案,我们探索了图案尺寸对润湿性和断裂行为的影响,为优化表面处理以增强材料性能提供了新的见解。图案尺寸范围从微米到毫米,参考样品,包括完全未经处理和完全激光处理的表面,也准备和测试。润湿性评估显示,增加激光处理面积分数显著增强了润湿性。微纹与大纹之间存在明显差异,大纹改变了润湿区形状,减小了有效接触角。这些发现强调了模式几何形状与润湿性之间的直接联系,这对于预测和控制裂缝能非常重要。激光处理对环氧铝粘接材料的断裂能和破坏模式有较大影响。未处理的样品在较低的断裂能值下出现粘接破坏,而完全处理的样品在断裂能高9倍的情况下出现粘接破坏。中间案例显示两种失效模式的混合。研究人员开发了理论和数值模型来预测和解释这些实验结果,强调表面图案尺寸显著影响附着和断裂性能。结果表明,仅通过处理面积分数不能唯一地预测断裂能,强调了精确表面图案控制裂纹扩展阻力的潜力,并表明润湿性与断裂能之间存在关系。
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来源期刊
Surfaces and Interfaces
Surfaces and Interfaces Chemistry-General Chemistry
CiteScore
8.50
自引率
6.50%
发文量
753
审稿时长
35 days
期刊介绍: The aim of the journal is to provide a respectful outlet for ''sound science'' papers in all research areas on surfaces and interfaces. We define sound science papers as papers that describe new and well-executed research, but that do not necessarily provide brand new insights or are merely a description of research results. Surfaces and Interfaces publishes research papers in all fields of surface science which may not always find the right home on first submission to our Elsevier sister journals (Applied Surface, Surface and Coatings Technology, Thin Solid Films)
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