Mohammad Reza Ahmadi, Effat Jamalizadeh, S. Yousef Ebrahimipour, Ghasem Sargazi
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引用次数: 0
Abstract
In this study, cobalt(II) and copper(II) metal–organic frameworks (MOFs) were synthesized using conventional reverse micelle (RM) and ultrasonic-assisted reverse micelle (UARM). The UARM method demonstrated superior efficacy in producing MOFs with improved properties. The CO2 adsorption properties of the synthesized MOFs were investigated using a volumetric adsorption apparatus. The adsorption isotherms were analyzed using various isotherm models, including Langmuir, Freundlich, Dubinin–Radushkevich, and Temkin. Thermodynamic parameters were calculated to understand the nature of the adsorption process. Based on RSM optimization, the capability of Co-MOF was estimated to be about 8.48 mmol/g. The enhanced adsorption performance was attributed to the efficient surface area, surface properties, and strong interaction between the CO2 molecules and the MOF surface.
期刊介绍：
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
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