The Photochemistry of Amino Acids Produced on the Polar Cryovolcanic Regions of Titan

IF 2.9 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ACS Earth and Space Chemistry Pub Date : 2025-03-08 DOI:10.1021/acsearthspacechem.4c00376
Diogo Gonçalves, Florence Hofmann, Severin Wipf, Riccardo Giovanni Urso, Jana Bocková, Cornelia Meinert, Paul Brandon Rimmer, Gautam Dutta Stroscio, Nir Goldman, Andreas Elsaesser, Bruno Pedras and Zita Martins*, 
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Abstract

The cryovolcanic regions of Titan offer transient opportunities for prebiotic molecules to exist in water–ammonia solutions on the surface of the Saturnian moon. The upcoming NASA’s Dragonfly mission will search for high nitrogen concentrations and amino acids on Titan’s equatorial terrains. Cryovolcanic features, however, are most common on the polar regions. To mitigate the distance, bubble bursting may encapsulate the prebiotic molecules into aerosols, which Titan’s Hadley circulation would subsequently transport to the equator. We investigate whether alanine and glycine survive this meridional journey. Despite the unconstrained meridional wind velocities, our results suggest that the amino acids can survive the transport through the mesosphere. Dragonfly may find cryo-volcanogenic amino acids on Titan’s equator. Further, the interaction between the two amino acids increased 10-fold the photodegradation rate of glycine. We justify it based on changes in the environment polarity.

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土卫六极地冰冻火山区产生的氨基酸的光化学
土卫六的低温火山区为生命元分子在土卫六表面的水-氨溶液中存在提供了短暂的机会。即将到来的美国宇航局蜻蜓任务将在土卫六的赤道地形上寻找高浓度的氮和氨基酸。然而,冰冻火山的特征在极地地区最为常见。为了减少距离,气泡破裂可能会将益生元分子封装成气溶胶,随后土卫六的哈德利环流将其运送到赤道。我们研究丙氨酸和甘氨酸是否能在这段经向旅程中存活下来。尽管经向风速不受限制,但我们的结果表明氨基酸可以在中间层的运输中存活下来。蜻蜓可能会在土卫六的赤道上发现低温火山氨基酸。此外,两种氨基酸之间的相互作用使甘氨酸的光降解率提高了10倍。我们根据环境极性的变化来证明这一点。
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来源期刊
ACS Earth and Space Chemistry
ACS Earth and Space Chemistry Earth and Planetary Sciences-Geochemistry and Petrology
CiteScore
5.30
自引率
11.80%
发文量
249
期刊介绍: The scope of ACS Earth and Space Chemistry includes the application of analytical, experimental and theoretical chemistry to investigate research questions relevant to the Earth and Space. The journal encompasses the highly interdisciplinary nature of research in this area, while emphasizing chemistry and chemical research tools as the unifying theme. The journal publishes broadly in the domains of high- and low-temperature geochemistry, atmospheric chemistry, marine chemistry, planetary chemistry, astrochemistry, and analytical geochemistry. ACS Earth and Space Chemistry publishes Articles, Letters, Reviews, and Features to provide flexible formats to readily communicate all aspects of research in these fields.
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